Design of artificial enzymes bearing several active centers: New trends, opportunities and problems

D Carballares, R Morellon-Sterling… - International Journal of …, 2022 - mdpi.com
Harnessing enzymes which possess several catalytic activities is a topic where intense
research has been carried out, mainly coupled with the development of cascade reactions …

[HTML][HTML] Transfer hydrogenation catalysis in cells

S Banerjee, PJ Sadler - RSC Chemical Biology, 2021 - pubs.rsc.org
Hydrogenation reactions in biology are usually carried out by enzymes with nicotinamide
adenine dinucleotide (NAD (P) H) or flavin mononucleotide (FAMH2)/flavinadenine …

The various levels of integration of chemo-and bio-catalysis towards hybrid catalysis

E Heuson, F Dumeignil - Catalysis Science & Technology, 2020 - pubs.rsc.org
Combining catalysts is not a recent concept. For several decades, it has enabled the
development of processes that are more economical in terms of solvents, energy, and …

Integration of CdS with a Fiber-Based Cadmium Coordination Polymer for Turning On Photocatalytic Oxidative Coupling Reactions

C Huang, D Wang, D Zhang, Z Shao… - Crystal Growth & …, 2022 - ACS Publications
Accurate control over the structure and optoelectronic properties of inorganic
semiconductors and coordination polymers (CPs) to fabricate hybrid composites has …

Fe(OTf)3- and γ-Cyclodextrin-Catalyzed Hydroamination of Alkenes with Carbazoles

EK Xiao, XT Wu, F Ma, X Feng, P Chen, YJ Jiang - Organic Letters, 2020 - ACS Publications
A Fe (OTf) 3-and γ-cyclodextrin catalyzed hydroamination of alkenes with carbazoles is
demonstrated. This biomimetic-catalyst-oriented sustainable and green method could …

[HTML][HTML] Design and directed evolution of noncanonical β-stereoselective metalloglycosidases

WJ Jeong, WJ Song - Nature Communications, 2022 - nature.com
Metallohydrolases are ubiquitous in nearly all subclasses of hydrolases, utilizing metal
elements to activate a water molecule and facilitate its subsequent dissociation of diverse …

Artificial metalloenzyme with peroxidase-like activity based on periodic mesoporous organosilica with ionic-liquid framework

S Abedanzadeh, B Karimi, Z Moosavi-Movahedi… - Microporous and …, 2023 - Elsevier
Artificial enzymes were developed as alternatives to natural enzymes. Considering the
unique characteristics of periodic mesoporous organosilica (PMO) materials, a rational …

Artificial metalloenzymes in a nutshell: the quartet for efficient catalysis

P Ebensperger, C Jessen-Trefzer - Biological Chemistry, 2022 - degruyter.com
Artificial metalloenzymes combine the inherent reactivity of transition metal catalysis with the
sophisticated reaction control of natural enzymes. By providing new opportunities in …

Kinetic Probes of the Origin of Activity in MOF-Based C–H Oxidation Catalysis

A Sur, NB Jernigan, DC Powers - ACS Catalysis, 2022 - ACS Publications
The development of homogeneous catalysis is enabled by the availability of a rich toolkit of
kinetics experiments, such as the Hg-drop test, that differentiate catalytic activity at ligand …

Well-dispersed Pt nanoparticles with tunable sizes on dendritic porous silica nanospheres as an artificial enzyme

X Wang, M Yu, X Li, Y Luan, X Du - Journal of Alloys and Compounds, 2021 - Elsevier
Due to excellent performances such as superior catalytic activity, high stability and
convenient synthesis, the artificial enzymes with high efficiency gain significant attention in …