Conspectus The formation and study of molecules that model the sp-hybridized carbon
allotrope, carbyne, is a challenging field of synthetic physical organic chemistry. The target …

In the past decade, boron difluoride formazanate dyes have gained considerable attention
due to their redox activity, high absorption and emission intensities, chemical stability across …

Extended conjugated polyynes provide models for the elusive sp carbon polymer carbyne,
but progress has been hampered by numerous synthetic challenges. Stabilities appear to be …

Four-coordinated boron complexes are fascinating scaffolds for achieving functional
luminescent materials because of their superior emission properties, biocompatibility, and …

Polyynes are one-dimensional carbon atomic wires possessing sp hybridization and
alternating triple and single bonds. Their electronic structure is particularly attractive and has …

Carbon materials have long been a subject of study, offering diverse properties based on
their hybridized structures. Except sp 2-hybridized graphene and carbon nanotubes, the …

Dye‐dye conjugates have attracted significant interest for their utility in applications such as
bioimaging, theranostics, and light‐harvesting. Many classes of organic dyes have been …

Since the Nobel prize winning discovery that polyacetylene could act as a semiconductor,
there has been tremendous efforts dedicated to understanding and harnessing the unusual …

Abstract 𝜋‐Conjugated polymers, including those based on acetylenic repeating units, are
an exciting class of materials that offer narrow optical band gaps and tunable frontier orbital …

Polyyne bridges have attracted extensive interest as molecular wires due to their shallow
distance dependence during charge transfer. Here, we investigate whether triplet energy …