Stereochemical enhancement of polymer properties

JC Worch, H Prydderch, S Jimaja, P Bexis… - Nature Reviews …, 2019 - nature.com
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …

Non‐isocyanate polyurethanes: synthesis, properties, and applications

G Rokicki, PG Parzuchowski… - Polymers for Advanced …, 2015 - Wiley Online Library
Conventional polyurethanes are typically obtained from polyisocyanates, polyols, and chain
extenders. The main starting materials—isocyanates used in this process—raise severe …

Poly (trimethylene carbonate)-based polymers engineered for biodegradable functional biomaterials

K Fukushima - Biomaterials science, 2016 - pubs.rsc.org
Aliphatic polycarbonates have drawn attention as biodegradable polymers that can be
applied to a broad range of resorbable medical devices. In particular, poly (trimethylene …

Organocatalysis: opportunities and challenges for polymer synthesis

MK Kiesewetter, EJ Shin, JL Hedrick… - …, 2010 - ACS Publications
Organocatalysis offers a number of opportunities in polymer synthesis and was among the
earliest methods of catalyzing the synthesis of polyesters. In the following Perspective we …

Recent advances in stereocomplexation of enantiomeric PLA-based copolymers and applications

Z Li, BH Tan, T Lin, C He - Progress in Polymer Science, 2016 - Elsevier
Poly (lactic acid) or poly (lactide)(PLA) is a biodegradable and biocompatible thermoplastic
polymer, being derived from renewable resources such as corn and sugar cane. The …

[HTML][HTML] Synthesis and post-polymerisation modifications of aliphatic poly (carbonate) s prepared by ring-opening polymerisation

S Tempelaar, L Mespouille, O Coulembier… - Chemical Society …, 2013 - pubs.rsc.org
Owing to their low toxicity, biocompatibility and biodegradability, aliphatic poly (carbonate) s
have been widely studied as materials for biomedical application. Furthermore, the synthetic …

Cylindrical micelles from the living crystallization-driven self-assembly of poly (lactide)-containing block copolymers

N Petzetakis, AP Dove, RK O'Reilly - Chemical Science, 2011 - pubs.rsc.org
The synthesis and self-assembly of poly (lactide)-b-poly (acrylic acid) and poly (lactide)-b-
poly (dimethylaminoethylacrylate) block copolymers by a combination of ring-opening …

Mixed micelles self-assembled from block copolymers for drug delivery

ABE Attia, ZY Ong, JL Hedrick, PP Lee, PLR Ee… - Current Opinion in …, 2011 - Elsevier
Mixed micelles self-assembled from two or more dissimilar block copolymers provide a
direct and convenient approach to improve physical stability and enhance drug loading …

Macromolecular architectures through organocatalysis

S Hu, J Zhao, G Zhang, H Schlaad - Progress in Polymer Science, 2017 - Elsevier
In virtue of the rising demand for metal-free polymeric materials, organocatalytic
polymerization has emerged and blossomed unprecedentedly in the past 15 years into an …

Renaissance of aliphatic polycarbonates: New techniques and biomedical applications

J Xu, E Feng, J Song - Journal of Applied Polymer Science, 2014 - Wiley Online Library
Aliphatic polycarbonates (APCs) were discovered a long time ago, with their conventional
applications mostly limited to low‐molecular‐weight oligomeric intermediates for …