The order–disorder conundrum: a trade-off between crystalline and amorphous porous organic polymers for task-specific applications

A Giri, Y Khakre, G Shreeraj, TK Dutta… - Journal of Materials …, 2022 - pubs.rsc.org
Porous organic polymers (POPs) have received increasing attention due to their properties,
such as permanent porosity with tunable pore size, robust structure, high surface area, and …

Pd/Cu-catalyzed sonogashira cross-coupling polycondensation: A promising approach for synthesizing conjugated polymers with useful applications

B Amna, A Ateş, T Ozturk - European Polymer Journal, 2023 - Elsevier
Sonogashira cross-coupling polycondensation has been one of the most useful tools for the
construction of conjugated polymers with useful properties for multiple applications …

Design and synthesis of bifunctional conjugated microporous polymers containing tetraphenylethene and bisulfone units for energy storage and fluorescent sensing of …

MG Mohamed, HY Hu, S Santhoshkumar… - Colloids and Surfaces A …, 2024 - Elsevier
In this study, we successfully used the Suzuki-Miyaura reaction to prepare three novel
conjugated microporous polymers (CMPs) that include tetraphenylethene (TPE): TPE-Ph-Th …

In Situ Organized Pd and Au Nanoparticles in a Naphthalene-Based Imine-Linked Covalent Triazine Framework for Catalytic Suzuki Reactions and H2 Generation …

N Nouruzi, M Dinari, B Gholipour… - ACS Applied Nano …, 2022 - ACS Publications
Herein, a naphthalene-based imine-linked covalent triazine framework (NICTF) as a triazine-
based covalent organic framework (COF) was obtained. The mesochannels of NICTF COF …

Photo‐Modulating CO2 Uptake of Hypercross‐linked Polymers Upcycled from Polystyrene Waste

A Liu, C Mollart, A Trewin, X Fan, CH Lau - ChemSusChem, 2023 - Wiley Online Library
Incorporating photo‐switches into skeletal structures of microporous materials or as guest
molecules yield photo‐responsive materials for low‐energy CO2 capture but at the expense …

Tuning (Photo) Electronic Properties of an Electron Deficient Porous Polymer via n‐Doping with Tetrathiafulvalene

H Bildirir, M García‐Tecedor, M Gomez‐Mendoza… - Small, 2024 - Wiley Online Library
Charge‐transfer complex formation within the pores of porous polymers is an efficient way to
tune their electronical properties. Introduction of electron accepting guests to the electron …

Conjugated microporous polymer frameworks for sustainable energy materials–elucidating the influence of solvents on the porosity properties for future design …

C Mollart, A Trewin - Journal of Materials Chemistry A, 2024 - pubs.rsc.org
Since 2010 the influence of reaction solvent choice on the porosity of conjugated
microporous polymers (CMPs) has been known, but never fully understood. This means that …

Mesoscale artificial synthesis of conjugated microporous polymers

C Mollart, B Ciborowski, A Trewin - Molecular Systems Design & …, 2023 - pubs.rsc.org
This work reports the mesoscale artificial synthesis of a conjugated microporous polymer,
CMP-1, using a hybrid coarse-grained methodology. Whilst using a coarse grain approach …

Artificial synthesis of covalent triazine frameworks for local structure and property determination

C Mollart, S Holcroft, MJG Peach, A Rowling… - Physical Chemistry …, 2022 - pubs.rsc.org
Here we show an 'artificial synthesis' method for covalent triazine framework (CTF)
materials, enabling localised structural features to be incorporated that result directly from …

What is Nanoarchitectonics: Origin and Task

K Ariga, O Azzaroni - 2022 - books.rsc.org
But, in their primitive nanotechnology approach, these craftsmen were not able to exert
control over the composition, morphology, and dimensions of these materials. Indeed, they …