STM studies of photochemistry and plasmon chemistry on metal surfaces

E Kazuma, J Jung, H Ueba, M Trenary, Y Kim - Progress in Surface Science, 2018 - Elsevier
We review our recent studies of photochemistry and plasmon chemistry of dimethyl
disulfide,(CH 3 S) 2, molecules adsorbed on metal surfaces using a scanning tunneling …

Direct observation of photoinduced tautomerization in single molecules at a metal surface

H Böckmann, S Liu, J Mielke, S Gawinkowski… - Nano Letters, 2016 - ACS Publications
Molecular switches are of fundamental importance in nature, and light is an important
stimulus to selectively drive the switching process. However, the local dynamics of a …

Photo-regulation of 2D supramolecular self-assembly: On-surface photochemistry studied by STM

HL Dai, YF Geng, QD Zeng, C Wang - Chinese Chemical Letters, 2017 - Elsevier
During the past few years, regulation and controlling of the two-dimension (2D) self-
assembled supramolecular structure on surface have drawn increasing attention in …

Adsorption and reversible conformational change of a thiophene based molecule on Au (111)

S Sarkar, KH Au-Yeung, T Kühne, A Waentig… - Scientific reports, 2023 - nature.com
We present a low temperature scanning tunneling microscope investigation of a prochiral
thiophene-based molecule that self-assembles forming islands with different domains on the …

Near-field enhanced photochemistry of single molecules in a scanning tunneling microscope junction

H Böckmann, S Gawinkowski, J Waluk… - Nano Letters, 2018 - ACS Publications
Optical near-field excitation of metallic nanostructures can be used to enhance
photochemical reactions. The enhancement under visible light illumination is of particular …

Molecular switching on graphyne and graphdiyne: Realizing functional carbon networks in synergy with graphene

SC Shekar, RS Swathi - Carbon, 2018 - Elsevier
Molecular switches have been promising candidates in the context of information storage,
sensors, optical devices, etc. and play a prominent role in molecular nanotechnology …

Exciton splitting of adsorbed and Free 4-Nitroazobenzene dimers: a quantum chemical study

E Titov, P Saalfrank - The Journal of Physical Chemistry A, 2016 - ACS Publications
Molecular photoswitches such as azobenzenes, which undergo photochemical trans↔ cis
isomerizations, are often mounted for possible applications on a surface and/or surrounded …

Light-Induced Quantitative and Electrical-Field-Induced Barrierless Switching of Spiropyran Derivative on Graphite Surface

H Malik, T Halbritter, A Heckel… - The Journal of Physical …, 2021 - ACS Publications
A new class of pyridine-based spiropyran (SP) shows photoinduced reversible switching
between the closed SP and ring-opened merocyanine (MC). We show that a condensed …

Dissociation of Single O2 Molecules on Ag(110) by Electrons, Holes, and Localized Surface Plasmons

M Lee, E Kazuma, J Jung, M Trenary… - The Chemical …, 2022 - Wiley Online Library
A detailed understanding of the dissociation of O2 molecules on metal surfaces induced by
various excitation sources, electrons/holes, light, and localized surface plasmons, is crucial …

Induced growth from a Ag gas on Cu (111)

C Sprodowski, K Morgenstern - The Journal of Physical Chemistry …, 2019 - ACS Publications
We investigate the induced growth of a Ag layer on a Cu (111) surface by variable low-
temperature scanning tunneling microscopy between 100 and 140 K at submonolayer …