Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Design and fabrication of mesoporous heterogeneous basic catalysts

LB Sun, XQ Liu, HC Zhou - Chemical Society Reviews, 2015 - pubs.rsc.org
Mesoporous solid bases are extremely desirable in green catalytic processes, due to their
advantages of accelerated mass transport, negligible corrosion, and easy separation. Great …

Sulfonic acid functionalized graphitic carbon nitride as solid acid–base bifunctional catalyst for Knoevenagel condensation and multicomponent tandem reactions

P Choudhary, A Sen, A Kumar, S Dhingra… - Materials Chemistry …, 2021 - pubs.rsc.org
Rational design and development of acid–base bifunctional heterogeneous catalysts for
organic synthesis is a tough process. A highly efficient, non-toxic, metal-free, low-cost, acid …

Heterogeneous catalysis for tandem reactions

MJ Climent, A Corma, S Iborra, MJ Sabater - ACS Catalysis, 2014 - ACS Publications
As long as the molecular complexity increases, the number of chemical transformations will
increase in parallel, becoming a highly demanding synthetic process in terms of time and …

Influence of zeolite ZSM-5 synthesis protocols and physicochemical properties in the methanol-to-olefin process

HS Kamaluddin, X Gong, P Ma, K Narasimharao… - Materials Today …, 2022 - Elsevier
To address the growing concerns regarding climate change and the depletion of fossil
resources, the zeolite ZSM-5 catalyzed methanol-to-olefin (MTO) process is considered to …

Cascade reactions catalyzed by metal organic frameworks

A Dhakshinamoorthy, H Garcia - ChemSusChem, 2014 - Wiley Online Library
Cascade or tandem reactions where two or more individual reactions are carried out in one
pot constitute a clear example of process intensification, targeting the maximization of spatial …

A spatially orthogonal hierarchically porous acid–base catalyst for cascade and antagonistic reactions

MA Isaacs, CMA Parlett, N Robinson, LJ Durndell… - Nature Catalysis, 2020 - nature.com
Complex organic molecules are of great importance to research and industrial chemistry
and typically synthesized from smaller building blocks by multistep reactions. The ability to …

Hollow hyper-cross-linked nanospheres with acid and base sites as efficient and water-stable catalysts for one-pot tandem reactions

Z Jia, K Wang, B Tan, Y Gu - ACS Catalysis, 2017 - ACS Publications
A task-specific functionalized hyper-cross-linked polymer (HCP) with hollow spherical
structure was synthesized by an easily accessible Friedel–Crafts reaction-based approach …

Catalytic properties of high nitrogen content carbonaceous materials

E Lepre, S Rat, C Cavedon… - Angewandte Chemie …, 2023 - Wiley Online Library
The influence of structural modifications on the catalytic activity of carbon materials is poorly
understood. A collection of carbonaceous materials with different pore networks and high …

Amino-and sulfo-bifunctionalized metal–organic frameworks: one-pot tandem catalysis and the catalytic sites

H Liu, FG Xi, W Sun, NN Yang, EQ Gao - Inorganic chemistry, 2016 - ACS Publications
New MIL-101 metal–organic frameworks (MOFs) dually functionalized with amino and sulfo
groups were fabricated by postsynthetic modification and used to catalyze one-pot …