Active Sites for CO2 Hydrogenation to Methanol: Mechanistic Insights and Reaction Control

H Zada, J Yu, J Sun - ChemSusChem, 2024 - Wiley Online Library
Catalytic CO2 conversion to methanol is a promising way to extenuate the adverse effects of
CO2 emission, global warming and energy shortage. Understanding the fundamental …

Controlling Metal‐Support Interactions to Engineer Highly Active and Stable Catalysts for COx Hydrogenation

S Chen - ChemSusChem, 2024 - Wiley Online Library
This perspective focuses on the modulation of metal‐support interaction (MSI) in catalysts for
COx hydrogenation, highlighting their profound impact on catalytic performance. Firstly, it …

Cation rearrangement at tetrahedral sites in the Cu/ZnAl2O4 spinel enhancing CO2 hydrogenation to methanol

L Song, G Liu, Z Qu - Applied Catalysis B: Environment and Energy, 2025 - Elsevier
Cu/ZnAl 2 O 4 spinel is a promising catalyst for CO 2-to-methanol due to its dual-site H 2
activation. However, controlling surface properties and metal-support interactions (MSI) …

Interfacial Site Density Engineering of ZnO/Cu Cube Inverse Catalysts for CO2 Hydrogenation Reactions

J Li, D Wang, W Xiong, J Ding, W Huang - ACS Catalysis, 2024 - ACS Publications
We report an approach to engineer the ZnO–Cu interfacial site density without changes of
the interfacial site structure on ZnO/Cu inverse catalysts by controlling the sizes of cubic Cu …

Constructing p–n Interfaces to Accelerate Carrier Separation in a Cu2O Photocathode through an In Situ Thermal Oxidation Method for Highly Active …

L Zheng, K Su, M Liu, J Gao, J He… - Crystal Growth & …, 2024 - ACS Publications
Cu2O-ZnO blended films with the structure of ZnO nanoparticles randomly distributed in the
Cu2O matrix were synthesized using an in situ thermal oxidation method. The microstructure …

Insight into the synergistic effect between plasma and oxygen vacancy in direct oxidation of CH4 to CH3OH by molecular O2 at mild condition

K Li, J Cai, Y Tao, Y Xing, Z Zhu, Z Lu… - Applied Catalysis A …, 2024 - Elsevier
The direct conversion of methane into the value-added chemical methanol using molecular
oxygen was investigated via plasma catalysis under mild condition. An efficient synergistic …

Exploring the Effect of the Solvothermal Time on the Structural Properties and Catalytic Activity of Cu-ZnO-ZrO2 Catalysts Synthesized by the Solvothermal Method for …

J Han, Y Liang, J Yu, G Wu, D Mao - Catalysts, 2024 - mdpi.com
A series of Cu-ZnO-ZrO2 (CCZ) catalysts were prepared by the solvothermal method with
different solvothermal times (1 h, 3 h, 6 h, and 12 h). The physicochemical properties of …

[HTML][HTML] The effects of metal oxides doping on the surface stability of In2O3 for CO2 hydrogenation

X Xu, Y Li, G Sun, J Cao, Y Wang, X Qin - AIP Advances, 2024 - pubs.aip.org
The significance of maintaining the surface stability of the In 2 O 3 catalyst in the conversion
of CO 2 to methanol through hydrogenation cannot be overstated. To improve surface …