Infrared ion spectroscopy: New opportunities for small-molecule identification in mass spectrometry-A tutorial perspective

J Martens, RE van Outersterp, RJ Vreeken… - Analytica chimica …, 2020 - Elsevier
Combining the individual analytical strengths of mass spectrometry and infrared
spectroscopy, infrared ion spectroscopy is increasingly recognized as a powerful tool for …

Zooming in on the initial steps of catalytic NO reduction using metal clusters

JM Bakker, F Mafuné - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The study of reactions relevant to heterogeneous catalysis on the surface of well-defined
metal clusters with full control over the number of consituent atoms and elemental …

Laboratory infrared spectra and fragmentation chemistry of sulfur allotropes

P Ferrari, G Berden, B Redlich, LBFM Waters… - Nature …, 2024 - nature.com
Sulfur is one of six life-essential elements, but its path from interstellar clouds to planets and
their atmospheres is not well known. Astronomical observations in dense clouds have so far …

Probing High-Order Transient Oligomers Using Ion Mobility Mass Spectrometry Coupled with Infrared Action Spectroscopy

S Bakels, S Daly, B Doğan, M Baerenfaenger… - Analytical …, 2024 - ACS Publications
Understanding and controlling peptide aggregation are critical due to its neurotoxic
implications. However, structural information about the key intermediates, the oligomers, is …

Stabilization of Glucosyl Dioxolenium Ions by “Dual Participation” of the 2,2-Dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) Protection Group for 1,2-cis-Glucosylation

WA Remmerswaal, KJ Houthuijs… - The Journal of …, 2022 - ACS Publications
The stereoselective introduction of glycosidic bonds is of paramount importance to
oligosaccharide synthesis. Among the various chemical strategies to steer stereoselectivity …

Unravelling the keto–enol tautomer dependent photochemistry and degradation pathways of the protonated UVA filter avobenzone

JA Berenbeim, NGK Wong, MCR Cockett… - The Journal of …, 2020 - ACS Publications
Avobenzone (AB) is a widely used UVA filter known to undergo irreversible
photodegradation. Here, we investigate the detailed pathways by which AB photodegrades …

Mass-spectrometry-based identification of synthetic drug isomers using infrared ion spectroscopy

RF Kranenburg, FAMG van Geenen, G Berden… - Analytical …, 2020 - ACS Publications
Infrared ion spectroscopy (IRIS), a mass-spectrometry-based technique exploiting resonant
infrared multiple photon dissociation (IRMPD), has been applied for the identification of …

Amadori rearrangement products as potential biomarkers for inborn errors of amino-acid metabolism

RE van Outersterp, SJ Moons, UFH Engelke… - Communications …, 2021 - nature.com
The identification of disease biomarkers plays a crucial role in developing diagnostic
strategies for inborn errors of metabolism and understanding their pathophysiology. A …

Isomer-Specific Two-Color Double-Resonance IR2MS3 Ion Spectroscopy Using a Single Laser: Application in the Identification of Novel Psychoactive Substances

FAMG van Geenen, RF Kranenburg… - Analytical …, 2021 - ACS Publications
The capability of an ion trap mass spectrometer to store ions for an arbitrary amount of time
allows the use of a single infrared (IR) laser to perform two-color double resonance IR–IR …

Evaluation of table-top lasers for routine infrared ion spectroscopy in the analytical laboratory

RE van Outersterp, J Martens, A Peremans, L Lamard… - Analyst, 2021 - pubs.rsc.org
Infrared ion spectroscopy is increasingly recognized as a method to identify mass
spectrometry-detected analytes in many (bio) chemical areas and its integration in analytical …