This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …

During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

Transition metal‐catalyzed enantioselective functionalization of C− H bond, the most
abundant functionality in organic molecules, has emerged as an expedient synthetic …

Axially chiral biaryl motifs are widely present in natural products and pharmaceuticals.
Moreover, they have been broadly used as privileged ligands in asymmetric catalysis. Over …

The development of catalytic enantioselective transformations, enabling the construction of
complex molecular scaffolds from simple precursors, has been a long-standing challenge in …

Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …

As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Transition-metal-catalyzed activation of C–H and C–C bonds is a challenging area in
synthetic organic chemistry. Among various methods to accomplish these processes, the …

The cleavage and reorganization of carbon− carbon bonds is an industrial key technology
for crude oil refining, carried out on a massive scale. In contrast, C− C bond cleavage …