Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Small-pore zeolites: synthesis and catalysis

M Dusselier, ME Davis - Chemical reviews, 2018 - ACS Publications
In the past decade or so, small-pore zeolites have received greater attention than large-and
medium-pore molecular sieves that have historically dominated the literature. This is …

A priori control of zeolite phase competition and intergrowth with high-throughput simulations

D Schwalbe-Koda, S Kwon, C Paris, E Bello-Jurado… - Science, 2021 - science.org
Zeolites are versatile catalysts and molecular sieves with large topological diversity, but
managing phase competition in zeolite synthesis is an empirical, labor-intensive task. In this …

Influence of framework Al density in chabazite zeolites on copper ion mobility and reactivity during NOx selective catalytic reduction with NH3

SH Krishna, A Goswami, Y Wang, CB Jones… - Nature Catalysis, 2023 - nature.com
Cu zeolites catalyse low-temperature (< 523 K) selective catalytic reduction (SCR) of
nitrogen oxides (NO x) via a redox cycle involving dynamic interconversion between NH3 …

Selective catalytic reduction of NOx with NH3: opportunities and challenges of Cu-based small-pore zeolites

Y Shan, J Du, Y Zhang, W Shan, X Shi… - National science …, 2021 - academic.oup.com
Zeolites, as efficient and stable catalysts, are widely used in the environmental catalysis
field. Typically, Cu-SSZ-13 with small-pore structure shows excellent catalytic activity for …

Catalysis in a cage: condition-dependent speciation and dynamics of exchanged Cu cations in SSZ-13 zeolites

C Paolucci, AA Parekh, I Khurana… - Journal of the …, 2016 - ACS Publications
The relationships among the macroscopic compositional parameters of a Cu-exchanged
SSZ-13 zeolite catalyst, the types and numbers of Cu active sites, and activity for the …

Continuous partial oxidation of methane to methanol catalyzed by diffusion-paired copper dimers in copper-exchanged zeolites

KT Dinh, MM Sullivan, K Narsimhan… - Journal of the …, 2019 - ACS Publications
Copper-exchanged zeolites can continuously and selectively catalyze the partial oxidation
of methane to methanol using only oxygen and water at low temperatures, but the genesis …

Engineering of transition metal catalysts confined in zeolites

N Kosinov, C Liu, EJM Hensen, EA Pidko - Chemistry of Materials, 2018 - ACS Publications
Transition metal–zeolite composites are versatile catalytic materials for a wide range of
industrial and lab-scale processes. Significant advances in fabrication and characterization …

Cu-CHA–a model system for applied selective redox catalysis

E Borfecchia, P Beato, S Svelle, U Olsbye… - Chemical Society …, 2018 - pubs.rsc.org
We review the structural chemistry and reactivity of copper-exchanged molecular sieves with
chabazite (CHA) topology, as an industrially applied catalyst in ammonia mediated …

Iron and copper active sites in zeolites and their correlation to metalloenzymes

BER Snyder, ML Bols, RA Schoonheydt… - Chemical …, 2017 - ACS Publications
Metal-exchanged zeolites are a class of heterogeneous catalysts that perform important
functions ranging from selective hydrocarbon oxidation to remediation of NO x pollutants …