Mechanistic aspects of C− H activation by Pt complexes

M Lersch, M Tilset - Chemical reviews, 2005 - ACS Publications
Hydrocarbons are readily available from inexpensive petrochemical and natural gas
feedstock and have been utilized as raw materials for the production of materials and energy …

The chemistry of binuclear palladium (II) and platinum (II) complexes

VK Jain, L Jain - Coordination Chemistry Reviews, 2005 - Elsevier
The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

Straightforward access to mono-and bis-cycloplatinated helicenes displaying circularly polarized phosphorescence by using crystallization resolution methods

C Shen, E Anger, M Srebro, N Vanthuyne, KK Deol… - Chemical …, 2014 - pubs.rsc.org
Enantiopure mono-cycloplatinated-[8] helicene and bis-cycloplatinated-[6] helicene
derivatives were prepared through column chromatography combined with crystallization of …

Dibenzometallacyclopentadienes, boroles and selected transition metal and main group heterocyclopentadienes: Synthesis, catalytic and optical properties

A Steffen, RM Ward, WD Jones, TB Marder - Coordination Chemistry …, 2010 - Elsevier
The review discusses the synthesis, structures and properties of transition metal and main-
group containing heterocyclopentadienes, with particular focus on …

Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes

M Crespo, M Martinez, SM Nabavizadeh… - Coordination Chemistry …, 2014 - Elsevier
The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

Piano-stool ruthenium (II) complexes with delayed cytotoxic activity: Origin of the lag time

L Rafols, D Josa, D Aguila, LA Barrios… - Inorganic …, 2021 - ACS Publications
We have recently reported a series of piano-stool ruthenium (II) complexes of the general
formula [RuCl2 (η6-arene)(P (1-pyrenyl) R2R3)] showing excellent cytotoxic activities …

[HTML][HTML] True and masked three-coordinate T-shaped platinum (II) intermediates

MA Ortuño, S Conejero… - Beilstein journal of organic …, 2013 - beilstein-journals.org
Although four-coordinate square-planar geometries, with a formally 16-electron counting,
are absolutely dominant in isolated Pt (II) complexes, three-coordinate, 14-electron Pt (II) …

Tuning N‐Heterocyclic Carbenes in T‐Shaped PtII Complexes for Intermolecular CH Bond Activation of Arenes

O Rivada‐Wheelaghan, MA Ortuño… - Angewandte Chemie …, 2012 - Wiley Online Library
CÀH bond activation of hydrocarbons promoted by PtII complexes have been intensively
studied since Shilov s first report on the catalytic conversion of methane into methanol and …

Selective Platinum-Catalyzed C− F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

HL Buckley, T Wang, O Tran, JA Love - Organometallics, 2009 - ACS Publications
[(CH3) 2Pt (μ-SMe2)] 2catalyzes the formation of aryl methyl ethers via selective C− F bond
activation of polyfluoroarylimines. This reaction is functional group tolerant and proceeds in …

Mechanistic Insight into the Protonolysis of the Pt− C Bond as a Model for C− H Bond Activation by Platinum (II) Complexes

R Romeo, G D'Amico - Organometallics, 2006 - ACS Publications
The kinetic and NMR features of the protonolysis reactions on platinum (II) alkyl complexes
of the types cis-[PtMe2L2],[PtMe2 (LL)], cis-[PtMeClL2], and [PtMeCl (LL)](L= PEt3, P (Pri) 3 …