Deep eutectic solvents: A review of fundamentals and applications

BB Hansen, S Spittle, B Chen, D Poe, Y Zhang… - Chemical …, 2020 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by
significant depressions in melting points compared to those of the neat constituent …

Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents

S Spittle, D Poe, B Doherty, C Kolodziej… - Nature …, 2022 - nature.com
Deep eutectic solvents (DESs) are an emerging class of non-aqueous solvents that are
potentially scalable, easy to prepare and functionalize for many applications ranging from …

Dynamics and proton conduction of heterogeneously confined imidazole in porous coordination polymers

L Cai, J Yang, Y Lai, Y Liang, R Zhang… - Angewandte …, 2023 - Wiley Online Library
The nanoconfinement of proton carrier molecules may contribute to the lowing of their proton
dissociation energy. However, the free proton transportation does not occur as easily as in …

[HTML][HTML] Communication: Correlation of terminal relaxation rate and viscosity enhancement in supramolecular small-molecule liquids

SP Bierwirth, C Gainaru, R Böhmer - The Journal of Chemical Physics, 2018 - pubs.aip.org
Monohydroxy alcohols with a large supramolecular Debye-type dielectric process often
exhibit a significant decoupling between the Debye mode and the structural relaxation …

The dielectric response of phenothiazine-based glass-formers with different molecular complexity

M Rams-Baron, A Jędrzejowska, K Jurkiewicz… - Scientific Reports, 2021 - nature.com
We examined a series of structurally related glass-forming liquids in which a phenothiazine-
based tricyclic core (PTZ) was modified by attaching n-alkyl chains of different lengths (n= 4 …

Ultrafast Proton Transfer Pathways Mediated by Amphoteric Imidazole

MA Codescu, T Kunze, M Weiß, M Brehm… - The Journal of …, 2023 - ACS Publications
Imidazole, being an amphoteric molecule, can act both as an acid and as a base. This
property enables imidazole, as an essential building block, to effectively facilitate proton …

The source of conductivity and proton dynamics study in TEMPO-oxidized cellulose doped with various heterocyclic molecules

ME Culica, M Avadanei, RI Baron, AL Chibac-Scutaru… - Cellulose, 2020 - Springer
Our manuscript focuses on the study of proton conductivity phenomena caused by a high
degree of mobility and dynamic movement of protons that occur in some hybrid composites …

Water-assisted proton conduction regulated by hydrophilic groups in metallo-hydrogen-bonded organic frameworks:“like-attracts-like” between hydrophilic groups and …

S Wang, F Xie, S Zhang, X Liang, Q Gao, Y Chen… - …, 2023 - pubs.rsc.org
The exploration of proton-conducting solid-state electrolytes operating under humidified
conditions is currently of considerable significance for fuel-cell technology. However, the …

[HTML][HTML] The dynamical signature and scaling of supramolecular assemblies

L Cai, P Yin - Supramolecular Materials, 2023 - Elsevier
We present a brief overview of current investigations on the dynamics of supramolecular
assemblies, with the focus on applying broadband dielectric spectroscopy (BDS) combined …

Studying structural and local dynamics in model H-bonded active ingredient—Curcumin in the supercooled and glassy states at various thermodynamic conditions

A Minecka, E Kamińska, D Heczko, K Jurkiewicz… - European Journal of …, 2019 - Elsevier
Different experimental techniques were applied to study thermal and structural properties,
strength of H-bonds, possible keto-enol tautomerism and molecular dynamics at various …