Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles
and other functional groups. α-Substituted vinyl azides (azido vinylidenes) are a special …

Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating
nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be …

Azobis tetrazole and triazole derivatives containing long catenated nitrogen atom chains are
of great interest as promising green energetic materials. However, these compounds often …

The unexpected synthesis of industrially important N‐vinyl amides directly from aldehydes
and α, β‐unsaturated N‐vinyl amides from esters is reported. This reaction probably …

In the current extensive review, we pay special attention to the progress in the synthesis of 2
H‐azirine. Content is organized by several main approaches for the synthesis of 2 H …

Abstract Irradiation of 2-azidovinylbenzene (1) in a cryogenic argon matrix with a 254 nm
bandpass filter results in 2-phenyl-2H-azirine (2) as the major product, some ketenimine 5 …

Abstract 2H-azirines have represented versatile building motifs in the domain of organic
chemistry owing to their excellent reaction activity induced by the high strain of the three …

Organic azides are one of the more adaptable functional groups in synthetic chemistry
because they react easily with both electrophiles and nucleophiles to form new C− N …

Vinyl azides are versatile reagents, owing to their dual functionality, consisting of both an
azido and alkene moiety. Although vinyl azides have been known for over a century, they …

Энергетические материалы (ЭМ) используются при ударно-волновой обработке
материалов, для получения новых материалов, в научных целях при исследовании …