Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

While 1, 1-diboryl (gem-diboryl) compounds are valuable synthetic building blocks,
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …

Organozinc compounds containing sp, sp2, and sp3 C–Zn moieties undergo transmetalation
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …

A MnI‐catalyzed hydroboration of terminal alkenes and a 1, 2‐diboration of terminal alkynes
with pinacolborane (HBPin) is described. For alkenes, anti‐Markovnikov hydroboration …

Polyborylated-alkenes are valuable polymetalloid reagents in modern organic synthesis,
providing access to a wide array of transformations, including the construction of multiple C …

The first nickel bis-boryl complexes cis-[Ni (iPr2ImMe) 2 (Bcat) 2], cis-[Ni (iPr2ImMe) 2 (Bpin)
2] and cis-[Ni (iPr2ImMe) 2 (Beg) 2] are reported, which were prepared via the reaction of a …

We report herein the catalytic triboration of terminal alkynes with B2pin2 (bis (pinacolato)
diboron) using readily available Cu (OAc) 2 and PnBu3. Various 1, 1, 2‐triborylalkenes, a …

Diboron reagents have been traditionally regarded as “Lewis acids”, which can react with
simple Lewis base to create a significant nucleophilic character in one of boryl moieties. In …