Allenes are the simplest class of cumulenes, with two contiguous C C bonds, and show
unique physical and chemical properties. These features make allenes particularly attractive …

The addition of an allylic organometallic compound to a carbonyl compound or an imine is of
great synthetic interest because in this reaction together with a new functionality (hydroxyl or …

What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Enantioselective allylation is a highly used organic reaction to prepare chiral homoallylic
alcohols and amines, which serve as important building blocks in the synthesis of a variety …

Four-coordinate organoboron derivatives present interesting chemical, physical, biological,
electronical, and optical properties. Given the increasing demand for the synthesis of smart …

The catalytic enantioselective allylation of aldehydes is a long-standing problem of
considerable interest to the chemical community. We disclose a new high-yielding and …

Organoboron compounds are useful in asymmetric synthesis. We have developed an
efficient methodology for the highly enantioselective synthesis of tertiary boronic esters from …

Allene–Verbindungen mit zwei benachbarten C C‐Bindungen–bilden die einfachste
Klasse unter den Cumulenen. Sie verfügen über außergewöhnliche physikalische und …

Disubstituted allylic boronic esters are not sufficiently reactive to react with ketones and
imines. However, they can be converted into the corresponding borinic esters by the …

Boronic esters react with 2-lithiated indoles to form boronate intermediates. The boronate
reacts with allylic acetates in the presence of (BINAP) Pd catalysts to allylate C3 concurrent …