Halogen bonding to amplify luminescence: a case study using a platinum cyclometalated complex

VV Sivchik, AI Solomatina, YT Chen… - Angewandte …, 2015 - Wiley Online Library
The cocrystallization of a weakly luminescent platinum complex [Pt (btpy)(PPh3)
Cl](1)(Hbtpy= 2‐(2benzothienyl) pyridine; emission quantum yield Φem= 0.03) with …

Highly luminescent half-lantern cyclometalated platinum (II) complex: synthesis, structure, luminescence studies, and reactivity.

V Sicilia, J Forniés, JM Casas, A Martín… - Inorganic …, 2012 - ACS Publications
The half-lantern compound [{Pt (bzq)(μ-C7H4NS2-κN, S)} 2]· Me2CO (1) was obtained by
reaction of equimolar amounts of potassium 2-mercaptobenzothiazolate (KC7H4NS2) and …

New Water Soluble and Luminescent Platinum(II) Compounds, Vapochromic Behavior of [K(H2O)][Pt(bzq)(CN)2], New Examples of the Influence of the Counterion on the …

J Forniés, S Fuertes, JA López, A Martín… - Inorganic …, 2008 - ACS Publications
This work describes the synthesis of compounds [Pt (C∧ N)(NCMe) 2] ClO4 (C∧ N= 7, 8-
benzoquinolinato (bzq), 2-phenylpyridinato (ppy)) and their use as precursors for the …

Bridging and terminal (phosphanido) platinum complexes

P Mastrorilli - European Journal of Inorganic Chemistry, 2008 - Wiley Online Library
The PR2–group (the phosphanido group, according to the modern IUPAC rules) possesses
a strong nucleophilicity, a high bridging tendency and a remarkable flexibility. This review …

Synthesis and luminescence of cyclometalated compounds with nitrile and isocyanide ligands

A Diez, J Fornies, S Fuertes, E Lalinde, C Larraz… - …, 2009 - ACS Publications
Mononuclear cationic cyclometalated palladium complexes [Pd (C∧ N)(NCMe) 2] ClO4 [C∧
N= benzoquinolinate (bzq) 1, 2-phenylpyridinate (ppy) 2], analogous to the previously …

Cyclometalated Platinum(II) Complexes Bearing Bidentate O,O′-Di(alkyl)dithiophosphate Ligands: Photoluminescence and Cytotoxic Properties

M Fereidoonnezhad, B Kaboudin, T Mirzaee… - …, 2017 - ACS Publications
Mononuclear complexes [Pt (ppy)(S∧ S)](1a, S∧ S= O, O′-di (cyclohexyl) dithiophosphate
(ctp); 2a, S∧ S= O, O′-di (butyl) dithiophosphate (btp)) and [Pt (bzq)(S∧ S)](1b, S∧ S= ctp; …

Luminescent cycloplatinated complexes with biologically relevant phosphine ligands: optical and cytotoxic properties

G Millán, N Giménez, R Lara, JR Berenguer… - Inorganic …, 2019 - ACS Publications
Two series of neutral luminescent pentafluorophenyl cycloplatinated (II) complexes [Pt (C^
N)(C6F5) L][C^ N= C-deprotonated 2-phenylpyridine (ppy; a), 2-(2, 4-difluorophenylpyridine …

Benzothiazole‐Based Cycloplatinated Chromophores: Synthetic, Optical, and Biological Studies

E Lalinde, R Lara, IP López, MT Moreno… - … A European Journal, 2018 - Wiley Online Library
Abstract Cycloplatinated complexes based on 2‐(4‐substituted) benzothiazole ligands of
type [Pt (R‐PBT‐κC, N) Cl (L)](PBT= 2‐phenylbenzothiazole; R= Br (1), Me2N (2); L …

Facile Metalation of Hbzq by [cis-Pt(C6F5)2(thf)2]: A Route to a Pentafluorophenyl Benzoquinolate Solvate Complex That Easily Coordinates Terminal Alkynes …

JR Berenguer, E Lalinde, MT Moreno… - Inorganic …, 2012 - ACS Publications
A new neutral cyclometalated platinum (II) solvate complex [cis-Pt (bzq)(C6F5)(acetone)](1)
has been prepared by easy C–H activation of 7, 8-benzo [h] quinoline on the coordination …

An extended chain and trinuclear complexes based on Pt (II)–M (M= Tl (I), Pb (II)) bonds: contrasting photophysical behavior

J Forniés, N Giménez, S Ibáñez, E Lalinde… - Inorganic …, 2015 - ACS Publications
The syntheses and structural characterizations of a Pt–Tl chain [{Pt (bzq)(C6F5) 2} Tl
(Me2CO)] n 1 and two trinuclear Pt2M clusters (NBu4)[{Pt (bzq)(C6F5) 2} 2Tl] 2 and [{Pt …