All‐carbon quaternary stereocenters have posed significant challenges in the synthesis of
complex natural products. These important structural motifs have inspired the development …

Asymmetric catalysis for chiral compound synthesis is a rapidly growing field in modern
organic chemistry. Asymmetric catalytic processes have been indispensable for the …

Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji
Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical …

In 1965 we reported that (ir-allyl) palladium chloride reacts with carbonucleophiles such as
malonates, acetoacetates, and enamines, thereby offering a new method for carbon-carbon …

0 OSiMe3 0"9 ~ Page 1 Pergamon 0040-4039(95)00306-1 Tetrahedron Letters, Vol. 36, No. 14,
pp. 2423-2426, 1995 Elsevier Science Ltd Printed in Great Britain 0040-4039/95 $9.50+0.00 A …

l-Proline rubidium salt catalyzes the asymmetric Michael addition of malonate anions to
prochiral enones and enals. This method can be applied to a wide range of substrates to …

Synthetic approaches to butenolides - Contemporary Organic Synthesis (RSC Publishing)
DOI:10.1039/CO9940100287 Royal Society of Chemistry View PDF Version DOI: 10.1039/CO9940100287 …

Für diesen Band, der sich in erster Linie an spezialisierte Katalyse-und
Organometallforscher wendet, haben die Herausgeber Informationen gesammelt und …

Capitalizing on versatile catalytic α, β-desaturation methods, strategies that directly
functionalize carbonyl compounds at their less-reactive β-positions have emerged over the …

The first asymmetric synthesis of pepluanol A (1) is presented. The synthesis route is very
concise (10 steps) and features a Curtin–Hammett-driven stereoconvergent intramolecular …