Evaluation of f-element borate chemistry
MA Silver, TE Albrecht-Schmitt - Coordination Chemistry Reviews, 2016 - Elsevier
The synthesis, structure elucidation, and spectroscopic measurements of a myriad of new, f-
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
Understanding the stabilization and tunability of divalent europium 2.2. 2B cryptates
TN Poe, MJ Beltrán-Leiva, C Celis-Barros… - Inorganic …, 2021 - ACS Publications
Lanthanides such as europium with more accessible divalent states are useful for studying
redox stability afforded by macrocyclic organic ligands. Substituted cryptands, such as 2.2 …
redox stability afforded by macrocyclic organic ligands. Substituted cryptands, such as 2.2 …
Structural and spectroscopic analysis of Ln (II) 18-crown-6 and benzo-18-crown-6 complexes (Ln= Sm, Eu, Yb)
TN Poe, S Molinari, S Justiniano… - Crystal Growth & …, 2021 - ACS Publications
Three Ln2+ 18-crown-6 complexes of the formula Ln (18-crown-6) I2 (Ln= Sm, Eu, Yb) were
isolated from the explicit synthesis of the corresponding LnI2 salts with 18-crown-6 and …
isolated from the explicit synthesis of the corresponding LnI2 salts with 18-crown-6 and …
Electronic structure and properties of berkelium iodates
The reaction of 249Bk (OH) 4 with iodate under hydrothermal conditions results in the
formation of Bk (IO3) 3 as the major product with trace amounts of Bk (IO3) 4 also …
formation of Bk (IO3) 3 as the major product with trace amounts of Bk (IO3) 4 also …
Tuning Mixed‐Valent Eu2+/Eu3+ in Strontium Formate Frameworks for Multichannel Photoluminescence
W Liu, L Liu, Y Wang, L Chen… - … A European Journal, 2016 - Wiley Online Library
Cooperative performance of mixed‐valent Eu2+/Eu3+ in single‐compound phosphors offers
significant advantages in color rendering and luminescence efficiency, but their synthesis is …
significant advantages in color rendering and luminescence efficiency, but their synthesis is …
A Mixed‐Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI
It is shown that UVO2+ ions can reside at UVIO22+ lattice sites during mild reduction and
crystallization process under solvothermal conditions, yielding a complicated and rare mixed …
crystallization process under solvothermal conditions, yielding a complicated and rare mixed …
Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared …
D Abeysinghe, MD Smith, J Yeon… - Crystal Growth & …, 2014 - ACS Publications
A new reduced vanadium oxalate, Ba3 [(VO) 2 (C2O4) 5 (H2O) 6]·(H2O) 3, 1, was
synthesized via a two-step, mild hydrothermal method using oxalic acid as the reducing …
synthesized via a two-step, mild hydrothermal method using oxalic acid as the reducing …
Crystal growth of four oxovanadium (IV) tartrates prepared via a mild two-step hydrothermal method: Observation of spin-dimer behavior and second harmonic …
AJ Cortese, B Wilkins, MD Smith, J Yeon… - Inorganic …, 2015 - ACS Publications
Four new oxovanadium (IV) tartrates, namely, A2 [(VO) 2 (C4H4O6)(C4H2O6)(H2O)
2]·(H2O) 2, where A= Cs, 1, Rb, 2; K2 [(VO) 2 (C4H2O6) 2 (H2O) 2]·(H2O) 2, 3; and Na2 …
2]·(H2O) 2, where A= Cs, 1, Rb, 2; K2 [(VO) 2 (C4H2O6) 2 (H2O) 2]·(H2O) 2, 3; and Na2 …
Ca[B8O11(OH)4] : Eu2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction
P Liang, WL Lian, ZH Liu - Chemistry–A European Journal, 2021 - Wiley Online Library
Highly efficient inorganic phosphors are crucial for solid‐state lighting. In this paper, a new
method of low‐temperature self‐reduction was used for preparing a highly efficient deep …
method of low‐temperature self‐reduction was used for preparing a highly efficient deep …
Chirality and Polarity in the f‐Block Borates M4[B16O26(OH)4(H2O)3Cl4] (M=Sm, Eu, Gd, Pu, Am, Cm, and Cf)
The reactions of trivalent lanthanides and actinides with molten boric acid in high chloride
concentrations result in the formation of M4 [B16O26 (OH) 4 (H2O) 3Cl4](M= Sm, Eu, Gd, Pu …
concentrations result in the formation of M4 [B16O26 (OH) 4 (H2O) 3Cl4](M= Sm, Eu, Gd, Pu …