Reversible magnesium and aluminium ions insertion in cation-deficient anatase TiO2

T Koketsu, J Ma, BJ Morgan, M Body, C Legein… - Nature materials, 2017 - nature.com
In contrast to monovalent lithium or sodium ions, the reversible insertion of multivalent ions
such as Mg2+ and Al3+ into electrode materials remains an elusive goal. Here, we …

NMR crystallography: Applications to inorganic materials

C Martineau - Solid state nuclear magnetic resonance, 2014 - Elsevier
Current developments of NMR crystallography as well as some recent applications to
diamagnetic inorganic solids are presented. First, we illustrate how solid-state NMR data …

Dramatic Enhancement of Rare-Earth Metal–Organic Framework Stability Via Metal Cluster Fluorination

MS Christian, KJ Fritzsching, JA Harvey… - JACS Au, 2022 - ACS Publications
Rare-earth polynuclear metal–organic frameworks (RE-MOFs) have demonstrated high
durability for caustic acid gas adsorption and separation based on gas adsorption to the …

Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response

SH Cho, S Ghosh, ZJ Berkson, JA Hachtel… - Chemistry of …, 2019 - ACS Publications
Cube-shaped nanocrystals (NCs) of conventional metals like gold and silver generally
exhibit localized surface plasmon resonance (LSPR) in the visible region with spectral …

Atomic Insights into Aluminium‐Ion Insertion in Defective Anatase for Batteries

C Legein, BJ Morgan, F Fayon… - Angewandte Chemie …, 2020 - Wiley Online Library
Aluminium batteries constitute a safe and sustainable high‐energy‐density electrochemical
energy‐storage solution. Viable Al‐ion batteries require suitable electrode materials that can …

Acidic properties of Al-rich ZSM-5 crystallized in strongly acidic fluoride medium

D Shi, G Fu, A Omran, KG Haw, L Zhu, R Ding… - Microporous and …, 2023 - Elsevier
The fluoride medium synthesis of zeolites, especially in the strongly acidic regions, yields
products with unique characteristics such as ultra-hydrophobic surfaces and defect-free …

Exploring the Sm1–xCaxF3–x Tysonite Solid Solution as a Solid-State Electrolyte: Relationships between Structural Features and F Ionic Conductivity

B Dieudonné, J Chable, F Mauvy… - The Journal of …, 2015 - ACS Publications
Pure tysonite Sm1–x Ca x F3–x solid solutions for 0.05≤ x≤ 0.17 have been prepared by
the solid-state route. For the first time, the partial Sm1–x Ca x F3–x solid solution is …

The key role of the composition and structural features in fluoride ion conductivity in tysonite Ce 1− x Sr x F 3− x solid solutions

B Dieudonné, J Chable, M Body, C Legein… - Dalton …, 2017 - pubs.rsc.org
Pure tysonite-type Ce1− xSrxF3− x solid solutions for 0≤ x< 0.15 were prepared by a solid-
state route at 900° C. The cell parameters follow Vegard's laws for 0≤ x≤ 0.10 and the …

Structural Modeling of O/F Correlated Disorder in TaOF3 and NbOF3–x(OH)x by Coupling Solid-State NMR and DFT Calculations

O Zakary, M Body, T Charpentier… - Inorganic …, 2023 - ACS Publications
The structure of MOF3 (M= Nb, Ta) compounds was precisely modeled by combining
powder X-ray diffraction, solid-state NMR spectroscopy, and semiempirical dispersion …

Study of NaF–AlF3 Melts by Coupling Molecular Dynamics, Density Functional Theory, and NMR Measurements

K Machado, D Zanghi, V Sarou-Kanian… - The Journal of …, 2017 - ACS Publications
Improvement of the industrial electrolytic process for aluminum production necessitates a
thorough understanding of the underlying ionic structure of the electrolyte, which mainly …