Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …

Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Coordination complexes of precious metals with the d6 valence electron configuration such
as Ru (II), Os (II) and Ir (III) are used for lighting applications, solar energy conversion and …

The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

Photoredox catalysis (PRC) has gained enormous and wide-ranging interest in recent years
but has also been subject to significant mechanistic uncertainty, even controversy. To …

Symmetry-breaking charge separation in molecular materials has attracted increasing
attention for optoelectronics based on single-material active layers. To this end, Fe (III) …

One-electron reduced photosensitizers have been invoked as crucial intermediates in
photoredox catalysis, including multiphoton excitation and electrophotocatalytic processes …

Iron N-heterocyclic carbene (FeNHC) complexes with long-lived charge transfer states are
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …

Aryl diazonium salts are ubiquitous building blocks in chemistry, as they are useful radical
precursors in organic synthesis as well as for the functionalization of solid materials. They …

Harnessing sunlight via photosensitizing molecules is key for novel optical applications and
solar-to-chemical energy conversion. Exploiting abundant metals such as iron is attractive …