Asymmetric construction of stereogenic carbon centers featuring a trifluoromethyl group from prochiral trifluoromethylated substrates
Organofluorine chemistry is an area of tremendous expansion. 1 The field of applications is
impressively wide in scope and has the potential to concern all fields of society. Indeed …
impressively wide in scope and has the potential to concern all fields of society. Indeed …
Asymmetric catalysis by architectural and functional molecular engineering: practical chemo‐and stereoselective hydrogenation of ketones
R Noyori, T Ohkuma - Angewandte Chemie International …, 2001 - Wiley Online Library
Hydrogenation is a core technology in chemical synthesis. High rates and selectivities are
attainable only by the coordination of structurally well‐designed catalysts and suitable …
attainable only by the coordination of structurally well‐designed catalysts and suitable …
Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions
Very few fields in chemistry have shown such a considerable interest as fluoroorganic
chemistry. Fluorine is perhaps the element that has experienced the greatest recent interest …
chemistry. Fluorine is perhaps the element that has experienced the greatest recent interest …
Recent advances in asymmetric phase‐transfer catalysis
T Ooi, K Maruoka - Angewandte Chemie International Edition, 2007 - Wiley Online Library
The use of chiral nonracemic onium salts and crown ethers as effective phase‐transfer
catalysts have been studied intensively primarily for enantioselective carbon–carbon or …
catalysts have been studied intensively primarily for enantioselective carbon–carbon or …
Modern synthetic methods for fluorine‐substituted target molecules
M Shimizu, T Hiyama - Angewandte Chemie International …, 2005 - Wiley Online Library
Fluorine has come to be recognized as a key element in materials science: in heat‐transfer
agents, liquid crystals, dyes, surfactants, plastics, elastomers, membranes, and other …
agents, liquid crystals, dyes, surfactants, plastics, elastomers, membranes, and other …
Enantioselective Formation of Stereogenic Carbon-Fluorine Centers by a Simple Catalytic Method Angew. Chem. Int. Ed. 2005, 44, 3703-3706.
M Marigo, D Fielenbach, A Braunton… - … . Chem. Int. Ed, 2005 - scholar.archive.org
Significance: Fluorinated molecules are very important in medicinal, agricultural and
materials science. This report is the first asymmetric fluorination of aldehydes with a simple …
materials science. This report is the first asymmetric fluorination of aldehydes with a simple …
Fluorinated carbonyl and olefinic compounds: basic character and asymmetric catalytic reactions
K Mikami, Y Itoh, M Yamanaka - Chemical reviews, 2004 - ACS Publications
The synthesis of organofluorine compounds has attracted explosive interest in recent years
due to the anomalous physical properties and decreased availability of these compounds …
due to the anomalous physical properties and decreased availability of these compounds …
N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation.
T Bootwicha, X Liu, R Pluta… - Angewandte Chemie …, 2013 - search.ebscohost.com
Cinchona alkaloid catalysts in combination with air‐and moisture‐stable N‐
trifluoromethylthiophthalimide as electrophilic SCF3 source enabled the catalytic …
trifluoromethylthiophthalimide as electrophilic SCF3 source enabled the catalytic …
Catalytic Enantioselective Fluorination of β‐Ketoesters
L Hintermann, A Togni - Angewandte Chemie International …, 2000 - Wiley Online Library
Isolated and crystallized [Ti (TADDOLato)] complexes were used as catalysts for the first
catalytic enantioselective (up to 90% ee) C− F bond‐forming reaction, the fluorination of β …
catalytic enantioselective (up to 90% ee) C− F bond‐forming reaction, the fluorination of β …
Exploration of fluorine chemistry at the multidisciplinary interface of chemistry and biology
I Ojima - The Journal of organic chemistry, 2013 - ACS Publications
Over the last three decades, my engagement in “fluorine chemistry” has evolved
substantially because of the multidisciplinary nature of the research programs. I began my …
substantially because of the multidisciplinary nature of the research programs. I began my …