Reaction dynamics studied via femtosecond X-ray liquidography at X-ray free-electron lasers
X-ray free-electron lasers (XFELs) provide femtosecond X-ray pulses suitable for pump–
probe time-resolved studies with a femtosecond time resolution. Since the advent of the first …
probe time-resolved studies with a femtosecond time resolution. Since the advent of the first …
Structural dynamics of proteins explored via time-resolved x-ray liquidography
The structure of a protein is closely related to its biological function. In this regard, structural
changes, as well as static structures, have been scrutinized as essential elements in …
changes, as well as static structures, have been scrutinized as essential elements in …
Solvent-dependent structural dynamics in the ultrafast photodissociation reaction of triiodide observed with time-resolved x-ray solution scattering
Resolving the structural dynamics of bond breaking, bond formation, and solvation is
required for a deeper understanding of solution-phase chemical reactions. In this work, we …
required for a deeper understanding of solution-phase chemical reactions. In this work, we …
Cerium photocatalyst in action: structural dynamics in the presence of substrate visualized via time-resolved x-ray liquidography
[Ce (III) Cl6] 3–, with its earth-abundant metal element, is a promising photocatalyst
facilitating carbon–halogen bond activation. Still, the structure of the reaction intermediate …
facilitating carbon–halogen bond activation. Still, the structure of the reaction intermediate …
The carbon–iodine bond cleavage and isomerization of iodoform visualized with femtosecond X-ray liquidography
Iodoform (CHI3) has garnered significant attention for its unique ability to induce photo-
cyclopropanation of olefins by releasing an iodine radical through C–I bond cleavage …
cyclopropanation of olefins by releasing an iodine radical through C–I bond cleavage …
Projection to extract the perpendicular component (PEPC) method for extracting kinetics from time-resolved data
Time-resolved x-ray liquidography (TRXL) is a potent method for investigating the structural
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography
The photoactivation mechanism of Os3 (CO) 12 at 400 nm is examined with time-resolved X-
ray liquidography. The data reveal two pathways: the vibrational relaxation following an …
ray liquidography. The data reveal two pathways: the vibrational relaxation following an …
Sensitivity of time‐resolved diffraction data to changes in internuclear distances and atomic positions
Time‐resolved x‐ray liquidography (TRXL) is a powerful technique to study molecular
structural dynamics in the solution phase. Typically, a TRXL experiment is conducted during …
structural dynamics in the solution phase. Typically, a TRXL experiment is conducted during …
Structural Dynamics of C2F4I2 in Cyclohexane Studied via Time-Resolved X-ray Liquidography
The halogen elimination of 1, 2-diiodoethane (C2H4I2) and 1, 2-diiodotetrafluoroethane
(C2F4I2) serves as a model reaction for investigating the influence of fluorination on reaction …
(C2F4I2) serves as a model reaction for investigating the influence of fluorination on reaction …
Model–state-of-the-art modelling and computational analysis of reactive sites: general discussion
B Chanbasha, M Costas, J Echeverría… - Faraday …, 2023 - pubs.rsc.org
Odile Eisenstein opened a discussion of the paper by Stuart A. Macgregor: You have found
an extended interaction between a hydrogen and the entire p-system of an arene ring. This …
an extended interaction between a hydrogen and the entire p-system of an arene ring. This …