The chemistry of [M3 (CO) 10 (μ-dppm)](M= Ru, Os): Activating and maintaining the trinuclear core
SE Kabir, G Hogarth - Coordination Chemistry Reviews, 2009 - Elsevier
Ruthenium and osmium dodecacarbonyls, M3 (CO) 12 (M= Ru, Os), find extensive use as
precursors towards a range of low-valent ruthenium and osmium compounds, being …
precursors towards a range of low-valent ruthenium and osmium compounds, being …
Diphosphine Isomerization and C−H and P−C Bond Cleavage Reactivity in the Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne …
WH Watson, G Wu, MG Richmond - Organometallics, 2006 - ACS Publications
The coordination and reactivity of the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-
cyclopentene-1, 3-dione (bpcd) with Os3 (CO) 10 (MeCN) 2 (1) has been explored. The …
cyclopentene-1, 3-dione (bpcd) with Os3 (CO) 10 (MeCN) 2 (1) has been explored. The …
Chelate and Bridge Diphosphine Isomerization: Triosmium and Triruthenium Clusters Containing 1, 1 '-Bis (diphenylphosphino) ferrocene (dppf)
The coordination mode of dppf {dppf= 1, 1 '-bis (diphenylphosphino) ferrocene} at triosmium
and triruthenium carbonyl clusters has been studied. Heating [Os3 (CO) 12] with dppf in the …
and triruthenium carbonyl clusters has been studied. Heating [Os3 (CO) 12] with dppf in the …
Reactions of Ru3 (CO) 12 with 1, 5-bis (diphenylphosphino) pentane: Synthesis, characterization, crystal structure, Hirshfeld surface and QTAIM Analysis of Ru3 (CO) …
Abstract Reactions of Ru 3 (CO) 12 with 1, 5-bis (diphenylphosphino) pentane (dpppe) in
THF induced by sodium benzophenone ketyl radical anion, resulted in the expected metal …
THF induced by sodium benzophenone ketyl radical anion, resulted in the expected metal …
Protonation and hydrogenation of triosmium clusters containing the bridging diphosphine ligands Ph2P (CH2nPPh2 (n 1 to 4)
AJ Deeming, SE Kabir - Journal of organometallic chemistry, 1988 - Elsevier
Members of the series of bridging diphosphine clusters [Os 3 (CO) 10 (diphos)] where
diphos Ph 2 P (CH 2 n PPh 2 [dppm (n= 1), dppe (n= 2), dppp (n= 3), or dppb (n= 4)] show …
diphos Ph 2 P (CH 2 n PPh 2 [dppm (n= 1), dppe (n= 2), dppp (n= 3), or dppb (n= 4)] show …
Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality
MS Hasan, MM Alam, MK Parvin, S Rajbangshi… - Journal of …, 2024 - Elsevier
The reactivity of saccharinate-bridged triosmium cluster [Os 3 (CO) 10 (μ-H)(μ-sac)](1) with
two diphosphines namely bis (diphenylphosphino) methane (dppm) and 1, 1′-bis …
two diphosphines namely bis (diphenylphosphino) methane (dppm) and 1, 1′-bis …
X-ray structure of [Os3 (CO) 10 (μ-Ph2PCH2PPh2)]
KA Azam, MB Hursthouse, SE Kabir, KMA Malik… - Journal of chemical …, 1999 - Springer
Abstract Decacarbonyl-μ-bis (diphenylphosphino) methane triosmium crystallizes in the
monoclinic space group P 2 1/c with a= 24.422 (5), b= 12.381 (2), c= 24.788 (5) Å, β= 103.69 …
monoclinic space group P 2 1/c with a= 24.422 (5), b= 12.381 (2), c= 24.788 (5) Å, β= 103.69 …
Thermolysis of [HOs3 (CO) 8 {µ3-Ph2PCH2P (Ph) C6H4}]: New Os2-and Os3-cluster products based on multiple CH bond activation of the bis (diphenylphosphino) …
Abstract Thermolysis of [HOs 3 (CO) 8 {µ 3-Ph 2 PCH 2 P (Ph) C 6 H 4}] in refluxing xylene
has been investigated, and three new polynuclear osmium compounds containing an …
has been investigated, and three new polynuclear osmium compounds containing an …
Reactions of perfluoroalkyl-substituted phosphines with osmium carbonyl clusters: crystal structures of bridged, linked and substituted derivatives
HG Ang, CH Koh, LL Koh, WL Kwik… - Journal of the …, 1993 - pubs.rsc.org
The secondary phosphine (CF3) 2C (OH) PH (CF3) has been shown from 1H and 19F NMR
and single-crystal X-ray diffraction studies to undergo P–C bond cleavage upon reaction …
and single-crystal X-ray diffraction studies to undergo P–C bond cleavage upon reaction …
Triosmium clusters containing bridging sulphur, hydrido, and diphosphine ligands: a study of hydride site preferences and mobility
KA Azam, SE Kabir, A Miah, MW Day… - Journal of …, 1992 - Elsevier
Reaction of dppm (Ph 2 PCH 2 PPh 2) with [OS 3 (μ-H) 2 (μ 3-S)(CO) 9] in refluxing toluene
leads to the cluster [Os 3 (μ-H) 2 (μ 3-S)(CO) 7 (dppm)](1)(34% yield), the crystal structure of …
leads to the cluster [Os 3 (μ-H) 2 (μ 3-S)(CO) 7 (dppm)](1)(34% yield), the crystal structure of …