The design of responsive luminescent lanthanide probes and sensors

D Parker, JD Fradgley, KL Wong - Chemical Society Reviews, 2021 - pubs.rsc.org
The principles of the design of responsive luminescent probes and sensors based on
lanthanide emission are summarised, based on a mechanistic understanding of their mode …

Spin–phonon coupling and magnetic relaxation in single-molecule magnets

JGC Kragskow, A Mattioni, JK Staab, D Reta… - Chemical Society …, 2023 - pubs.rsc.org
Electron–phonon coupling is important in many physical phenomena, eg photosynthesis,
catalysis and quantum information processing, but its impacts are difficult to grasp on the …

Molecular magnetism

NF Chilton - Annual Review of Materials Research, 2022 - annualreviews.org
Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Pseudocontact shifts in biomolecular NMR spectroscopy

T Müntener, D Joss, D Häussinger… - Chemical Reviews, 2022 - ACS Publications
Paramagnetic centers in biomolecules, such as specific metal ions that are bound to a
protein, affect the nuclei in their surrounding in various ways. One of these effects is the …

Origin of the anomalously low Raman exponents in single molecule magnets

L Gu, R Wu - Physical Review B, 2021 - APS
The Raman exponent of single molecular magnetic relaxation may take various unexpected
values because of rich phonon spectra and spin-phonon coupling of molecular crystals. We …

A journey in lanthanide coordination chemistry: from evaporable dimers to magnetic materials and luminescent devices

K Bernot, C Daiguebonne, G Calvez… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Lanthanide ions are prime ingredients for the design of compounds, materials,
and devices with unique magnetic and optical properties. Accordingly, coordination …

A surface coordination interphase stabilizes a solid‐state battery

YN Yang, FL Jiang, YQ Li, ZX Wang… - Angewandte Chemie …, 2021 - Wiley Online Library
Solid‐state electrolytes (SSEs) show potential in addressing the safety issues of liquid
batteries, but the poor interface contact between them and the electrodes hinders practical …

Optical spectroscopy as a tool for studying the solution chemistry of neodymium (III)

PR Nawrocki, TJ Sørensen - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
In nature, the elements of the inorganic part of the periodic table are found in three forms:
metals, ions in salts & minerals, and ions in solution. The ions may be coordinated to simple …

Lanthanide‐Based Molecular Cluster‐Aggregates: Optical Barcoding and White‐Light Emission with Nanosized {Ln20} Compounds

DA Gálico, AA Kitos, JS Ovens, FA Sigoli… - Angewandte …, 2021 - Wiley Online Library
Counterfeit goods represent a major problem to companies, governments, and customers,
affecting the global economy. In order to protect the authenticity of products and documents …

A dysprosium single molecule magnet outperforming current pseudocontact shift agents

FS Santana, M Perfetti, M Briganti, F Sacco… - Chemical …, 2022 - pubs.rsc.org
A common criterion for designing performant single molecule magnets and pseudocontact
shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex …