Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

Resolving heterogeneity problems and impurity artifacts in operationally homogeneous transition metal catalysts

RH Crabtree - Chemical reviews, 2012 - ACS Publications
Although already established as distinct areas of practice by chemists by the late 19th
century, a formal distinction between homogeneous and other types of catalysis was only …

Amine− and phosphine− borane adducts: new interest in old molecules

A Staubitz, APM Robertson, ME Sloan… - Chemical …, 2010 - ACS Publications
Chem. Rev. 2010, 110, 4023–4078 4023 10.1021/cr100105a 2010 American Chemical
Society Published on Web 07/14/2010 dates from the 19th century. Since 2000, these …

B–N compounds for chemical hydrogen storage

CW Hamilton, RT Baker, A Staubitz… - Chemical Society …, 2009 - pubs.rsc.org
Hydrogen storage for transportation applications requires high volumetric and gravimetric
storage capacity. B–N compounds are well suited as storage materials due to their light …

Ammonia borane as an efficient and lightweight hydrogen storage medium

B Peng, J Chen - Energy & Environmental Science, 2008 - pubs.rsc.org
Ammonia borane (NH3BH3, AB) containing 19.6 wt% hydrogen has been considered as a
promising candidate for on-board hydrogen storage applications on the way to the ideal …

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight …

A Staubitz, ME Sloan, APM Robertson… - Journal of the …, 2010 - ACS Publications
The catalytic dehydrocoupling/dehydrogenation of N-methylamine-borane, MeNH2· BH3 (7),
to yield the soluble, high molecular weight poly (N-methylaminoborane)(8a),[MeNH− BH2] n …

A single-component liquid-phase hydrogen storage material

W Luo, PG Campbell, LN Zakharov… - Journal of the American …, 2011 - ACS Publications
The current state-of-the-art for hydrogen storage is compressed H2 at 700 bar. The
development of a liquid-phase hydrogen storage material has the potential to take …

[PDF][PDF] Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues of …

A Staubitz, A Presaemsp14Soto… - … Chemie-German Edition, 2008 - academia.edu
Despite the historic analogy between boron–nitrogen compounds and those of carbon [1]
and the expanding interest in polymeric materials based on main-group elements,[2] …

Ammonia borane as a hydrogen carrier: dehydrogenation and regeneration

NC Smythe, JC Gordon - European Journal of Inorganic …, 2010 - Wiley Online Library
Interest in sustainable non‐hydrocarbon‐based fuels for transportation has grown as the
realization that the supply of fossil fuels is limited and the deleterious environmental effects …

Homogeneous catalytic dehydrocoupling/dehydrogenation of amine− borane adducts by early transition metal, group 4 metallocene complexes

ME Sloan, A Staubitz, TJ Clark… - Journal of the …, 2010 - ACS Publications
The efficient catalytic dehydrocoupling of a range of amine− borane adducts, R′ RNH· BH3
(R′= R= Me 1a; R′= R= i Pr 1b; R′= Me, R= CH2Ph 1c) by a series of group 4 …