Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N′-Disubstituted Bis(pyrazol-3-yl)pyridines

DY Aleshin, I Nikovskiy, VV Novikov, AV Polezhaev… - ACS …, 2021 - ACS Publications
Here, we report a combined study of the effects of two chemical modifications to an N, N′-
disubstituted bis (pyrazol-3-yl) pyridine (3-bpp) and of different solvents on the spin …

[HTML][HTML] Fine-tuning of the spin-crossover properties of Fe (III) complexes via ligand design

D Vidal, J Cirera, J Ribas-Arino - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Exploring the chemical space of a given ligand aiming to modulate its ligand field strength is
a versatile strategy for the fine-tuning of physical properties such as the transition …

Spin State Tunes Oxygen Atom Transfer towards FeIVO Formation in FeII Complexes

CE Castillo, I Gamba, L Vicens… - … A European Journal, 2021 - Wiley Online Library
Oxoiron (IV) complexes bearing tetradentate ligands have been extensively studied as
models for the active oxidants in non‐heme iron‐dependent enzymes. These species are …

[PDF][PDF] The supramolecular chemistry and magnetic properties of flexible tetrahedral cages and circular helicates.

C Kleinjan - 2020 - ir.canterbury.ac.nz
This thesis details the effects of introducing flexibility into otherwise rigid C₃ tertiary amine
ligands on the structural, host-guest, and magnetic properties of face-capped tetrahedral …