Glycerol as a potential renewable raw material for acrylic acid production

D Sun, Y Yamada, S Sato, W Ueda - Green Chemistry, 2017 - pubs.rsc.org
Production of fuels and chemicals from renewable biomass resources is an attractive way to
alleviate the shortage of fossil fuels and reduce CO2 emission. Glycerol is an important …

Environmental and economical perspectives of a glycerol biorefinery

GM Lari, G Pastore, M Haus, Y Ding… - Energy & …, 2018 - pubs.rsc.org
Glycerol conversion into chemicals and fuel additives is pursued to valorise a burgeoning by-
product in the bioenergy sector. To this aim, heterogeneous catalysts have been developed …

Conversion of glycerol to acrylic acid: a review of strategies, recent developments and prospects

UC Abubakar, Y Bansod, L Forster… - Reaction Chemistry & …, 2023 - pubs.rsc.org
Acrylic acid is an essential chemical and a vital intermediate used in the production of
various commodities and industrial chemicals. However, continued reliance on petroleum …

Identification of the catalytically active component of Cu–Zr–O catalyst for the hydrogenation of levulinic acid to γ-valerolactone

S Ishikawa, DR Jones, S Iqbal, C Reece, DJ Morgan… - Green …, 2017 - pubs.rsc.org
Cu–ZrO2 catalysts were synthesized by the methanothermal (Me) and oxalate gel
precipitation (Og) methods. Detailed characterization of the catalysts synthesized by the Me …

Microporous crystalline Mo–V mixed oxides for selective oxidations

S Ishikawa, W Ueda - Catalysis Science & Technology, 2016 - pubs.rsc.org
Recent developments of crystalline Mo3VOx catalysts (MoVO), a new type of oxidation
catalysts for selective oxidations of ethane to ethene and of acrolein to acrylic acid, are …

True catalytically active structure in Mo–V-based mixed oxide catalysts for selective oxidation of acrolein

S Ishikawa, Y Yamada, N Kashio, N Noda… - ACS …, 2021 - ACS Publications
Crystalline trigonal Mo3VO x (Tri-MoVO) catalyst is constructed of {Mo6O21} 6–pentagonal
units and octahedral {MO6} units that form hexagonal and heptagonal channels in the …

Redox Treatment of Orthorhombic Mo29V11O112 and Relationships between Crystal Structure, Microporosity and Catalytic Performance for Selective Oxidation of …

S Ishikawa, D Kobayashi, T Konya… - The Journal of …, 2015 - ACS Publications
Redox treatments of an orthorhombic Mo29V11O112 catalyst (MoVO) were conducted and
its crystal structure, microporosity, and catalytic activity were investigated. TPR and TG …

Pathways, mechanisms, and kinetics: a strategy to examine byproduct selectivity in partial oxidation catalytic transformations on reducible oxides

JH Miller, L Bui, A Bhan - Reaction Chemistry & Engineering, 2019 - pubs.rsc.org
Oxidative transformations of organic molecules over reducible oxides provide essential
routes for synthesis of high-value unsaturated or oxygen-containing organic compounds that …

Thermal treatments of precursors of molybdenum and vanadium oxides and the formed MoxVyOz phases active in the oxydehydration of glycerol

LG Possato, WH Cassinelli, CI Meyer, T Garetto… - Applied Catalysis A …, 2017 - Elsevier
This paper presents an in situ study of the crystallographic phases formed during the thermal
treatment of precursors of vanadium and molybdenum oxides, measured under synchrotron …

Synthesis of crystalline microporous Mo–V–bi oxide for selective (amm) oxidation of light alkanes

S Ishikawa, Y Goto, Y Kawahara, S Inukai… - Chemistry of …, 2017 - ACS Publications
Bismuth (Bi) was successfully introduced into the crystalline orthorhombic Mo3VO x (MoVO)
structure for the first time by using the ethylammonium cation (EtNH3+) as a structure …