The chemistry of Group 8 metal complexes with phosphinous acids and related POH ligands

J Francos, D Elorriaga, P Crochet… - Coordination Chemistry …, 2019 - Elsevier
Despite their inherent instability, phosphinous acids PR 2 OH have emerged in recent years
as a useful class of P-donor ligands for homogeneous catalysis. The present review article …

Synthesis and structure of arene ruthenium (II) benzhydrazone complexes: Antiproliferative activity, apoptosis induction and cell cycle analysis

RR Kumar, R Ramesh, JG Małecki - Journal of Organometallic Chemistry, 2018 - Elsevier
Synthesis of new half-sandwich ruthenium (II) complexes of the type [Ru (η 6-arene)(L)
Cl](arene= benzene or p-cymene; L= 1-pyrene-carboxaldehye benzhydrazone ligands) has …

Synthesis and characterisation of new pyrazole–phosphinite ligands and their ruthenium (II) arene complexes

R Tribó, S Muñoz, J Pons, R Yáñez… - Journal of …, 2005 - Elsevier
The new potentially bidentate pyrazole–phosphinite ligands [(3, 5-dimethyl-1H-pyrazol-1-yl)
methyl diphenylphosphinite](L1) and [2-(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl …

Reaction of platinum (II) derivatives with 1-hydroxyalkyl-3, 5-dimethylpyrazole ligands. Cleavage of the N (pz) C (sp3) bond. X-ray crystal structure of cis-[PtCl2 (HL2) …

A Boixassa, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2003 - Elsevier
The reactions of 1-hydroxymethyl-3, 5-dimethylpyrazole (HL1) and 1-(2-hydroxyethyl)-3, 5-
dimethylpyrazole (HL2) with several platinum starting materials ([PtCl2 (CH3CN) 2], cis-and …

Preparation of Diazoalkane Complexes of Ruthenium and Their Cyclization Reactions with Alkenes and Alkynes

G Albertin, S Antoniutti, A Botter, J Castro… - …, 2014 - ACS Publications
The diazoalkane complexes [Ru (η5-C5H5)(N2CAr1Ar2)(PPh3)(L)] BPh4 (1–5: Ar1= Ar2=
Ph (a), Ar1= Ph and Ar2= p-tolyl (b), Ar1Ar2= C12H8 (c), Ar1= Ph and Ar2= PhCO (d); L …

Synthesis, spectroscopic properties and structural characterisation of Pd (II) and Pt (II) complexes with 1, 3, 5-pyrazole derived ligands. Rotation around the metal–N …

V Montoya, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2005 - Elsevier
Reactions of ligands 1-ethyl-5-methyl-3-phenyl-1H-pyrazole (L1) and 5-methyl-1-octyl-3-
phenyl-1H-pyrazole (L2) with [PdCl2 (CH3CN) 2 and K2PtCl4 gave complexes trans-[MCl2 …

Synthesis of New PdII Complexes Containing a Thioether‐Pyrazole Hemilabile Ligand − Structural Analysis by 1H, 13C NMR Spectroscopy and Crystal Structure of [PdCl(bdtp …

J García‐Antón, J Pons, X Solans… - European Journal of …, 2003 - Wiley Online Library
Abstract Treatment of the ligand 1, 5‐bis (3, 5‐dimethyl‐1‐pyrazolyl)‐3‐thiapentane (bdtp)
with [PdCl2 (CH3CN) 2] led to a [PdCl2 (bdtp)] complex. Subsequent treatment of this …

Pyrazolic palladium compounds containing alcohol functionality: hindered rotation around Pd N bond

A Boixassa, J Pons, A Virgili, X Solans… - Inorganica chimica …, 2002 - Elsevier
Reactions of the ligands 1-hydroxymethyl-3, 5-dimethylpyrazole (HL1), 1-(2-hydroxyethyl)-3,
5-dimethylpyrazole (HL2) and 1-(3-hydroxypropyl)-3, 5-dimethylpyrazole (HL3) with [PdCl2 …

Synthesis, spectroscopic and electronic characterizations of two half sandwich ruthenium (II) complexes with 2-(2′-hydroxyphenyl)-benzoxazole and 4-picolinic acid …

JG Małecki, R Kruszynski, M Jaworska… - Journal of …, 2008 - Elsevier
The [(C6H6) RuCl (HPB)] and [(C6H6) RuCl2 (C5H4NCOOH)] complexes have been
prepared and studied by IR, UV–Vis spectroscopy and X-ray crystallography. The …

Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni (II), Pd (II) and Pt (II) complexes of didentate ligands with NS-donor set

J Garcı́a-Antón, J Pons, X Solans, M Font-Bardia… - Inorganica chimica …, 2003 - Elsevier
Thiolate-bridged dinuclear nickel (II), palladium (II) and platinum (II) complexes with N-(2-
mercaptoethyl)-3, 5-dimethylpyrazole (Hmed),[MCl (med)] 2 (M= Ni (1), Pd (2), Pt (3)), have …