Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

[HTML][HTML] Covalent on-surface polymerization

L Grill, S Hecht - Nature Chemistry, 2020 - nature.com
With the rapid development of scanning probe microscopy, it has become possible to study
polymerization processes on suitable surfaces at the atomic level and in real space. In the …

[HTML][HTML] Controlling on-surface polymerization by hierarchical and substrate-directed growth

L Lafferentz, V Eberhardt, C Dri, C Africh, G Comelli… - Nature …, 2012 - nature.com
A key challenge in the field of nanotechnology, in particular in the design of molecular
machines, novel materials or molecular electronics, is the bottom-up construction of …

On-surface synthesis of rylene-type graphene nanoribbons

H Zhang, H Lin, K Sun, L Chen… - Journal of the …, 2015 - ACS Publications
The narrowest armchair graphene nanoribbon (AGNR) with five carbons across the width of
the GNR (5-AGNR) was synthesized on Au (111) surfaces via sequential dehalogenation …

[HTML][HTML] Frontiers of on-surface synthesis: From principles to applications

Q Shen, HY Gao, H Fuchs - Nano Today, 2017 - Elsevier
On-surface synthesis is the bottom-up construction of covalent bonds between molecular
building blocks, which has been greatly developed during the past decade. Dozens of …

Single-molecule resolution of an organometallic intermediate in a surface-supported Ullmann coupling reaction

W Wang, X Shi, S Wang, MA Van Hove… - Journal of the American …, 2011 - ACS Publications
We have studied the organometallic intermediate of a surface-supported Ullmann coupling
reaction from 4, 4 ″-dibromo-p-terphenyl to poly (para-phenylene) by scanning tunneling …

On‐Surface Synthesis of Carbon Nanostructures

Q Sun, R Zhang, J Qiu, R Liu, W Xu - Advanced Materials, 2018 - Wiley Online Library
Novel carbon nanomaterials have aroused significant interest owing to their prospects in
various technological applications. The recently developed on‐surface synthesis strategy …

Covalent networks through on-surface chemistry in ultra-high vacuum: state-of-the-art and recent developments

G Franc, A Gourdon - Physical chemistry chemical physics, 2011 - pubs.rsc.org
The fabrication of large molecular devices, directly on surfaces in UHV conditions, by
covalent coupling of smaller precursors has become in the past years an attractive solution …

On-surface synthesis of cyclic organic molecules

J Méndez, MF López, JA Martín-Gago - Chemical Society Reviews, 2011 - pubs.rsc.org
Creating or connecting together large organic molecules, as polycyclic aromatic
hydrocarbons (PAH), by chemical reactions readily on surfaces is the first step to a true …

On‐Surface Reactions

R Lindner, A Kühnle - ChemPhysChem, 2015 - Wiley Online Library
On‐surface synthesis constitutes a rapidly growing field of research due to its promising
application for creating stable molecular structures on surfaces. While self‐assembled …