The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Over the past few decades, platinum has attracted remarkable attention and played an
important role in promoting construction of C–X (X= C, O, N, B, etc.) bonds in organometallic …

A Ni-catalyzed borylation via C–F activation is described. This protocol is distinguished by a
wide scope, including unactivated fluoroarenes, without compromising its efficiency and …

This manuscript describes the design, synthesis, characterization, and reactivity studies of
organometallic NiIII complexes of general structure TpNiIII (R)(R1)(Tp= tris (pyrazolyl) …

This communication describes the synthesis and reactivity of NiIV (aryl)(CF3) 2 complexes
supported by trispyrazolylborate and 4, 4′-di-tert-butylbipyridine ligands. We demonstrate …

This review highlights the use of a bisphosphine ligand group in homogeneous catalysis.
This ligand group is known as the Xantphos-like ligands, which are based on the generic …

Monodentate phosphine ligands are frequently employed in the Ni-catalyzed C–O
functionalization of aryl esters. However, the extensive body of preparative work on such …

The robust, high‐valent NiIV complex [(Py) 2NiIVF2 (CF3) 2](Py= pyridine) was synthesized
and fully characterized by NMR spectroscopy, X‐ray diffraction, and elemental analysis. It …

The past few decades have witnessed a complete renaissance in the field of Ni (IV)
catalysis. The properties of Ni (IV) complexes, such as, it undergoes rapid reductive …

This article describes the new economic decarboxylative trifluoromethylating reagent [Cu
(phen)(O2CCF3)](1; phen= 1, 10‐phenanthroline) and the efficient difluorocarbene …