Metal‐Organic Frameworks for Photocatalytic Water Splitting and CO2 Reduction

K Sun, Y Qian, HL Jiang - Angewandte Chemie, 2023 - Wiley Online Library
Photocatalytic water splitting and carbon dioxide (CO2) reduction provide promising
solutions to global energy and environmental issues. In recent years, metal‐organic …

Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production

JD Xiao, R Li, HL Jiang - Small Methods, 2023 - Wiley Online Library
Metal–organic frameworks (MOFs) represent a novel class of crystalline inorganic–organic
hybrid materials with tunable semiconducting behavior. MOFs have potential for application …

S‐Scheme Co9S8@Cd0.8Zn0.2S‐DETA Hierarchical Nanocages Bearing Organic CO2 Activators for Photocatalytic Syngas Production

B Su, M Zheng, W Lin, XF Lu, D Luan… - Advanced Energy …, 2023 - Wiley Online Library
Delicate modulations of CO2 activation and charge carrier separation/migration are
challenging, yet imperative to augment CO2 photoreduction efficiency. Herein, by supporting …

Integrating Enrichment, Reduction, and Oxidation Sites in One System for Artificial Photosynthetic Diluted CO2 Reduction

Y Yang, HY Zhang, Y Wang, LH Shao… - Advanced …, 2023 - Wiley Online Library
Artificial photosynthetic diluted CO2 reduction directly driven by natural sunlight is a
challenging, but promising way to realize carbon‐resources recycling utilization. Herein, a …

Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water

S Karmakar, S Barman, FA Rahimi, D Rambabu… - Nature …, 2023 - nature.com
In the quest for renewable fuel production, the selective conversion of CO2 to CH4 under
visible light in water is a leading-edge challenge considering the involvement of kinetically …

Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4

S Barman, A Singh, FA Rahimi… - Journal of the American …, 2021 - ACS Publications
Achieving more than a two-electron photochemical CO2 reduction process using a metal-
free system is quite exciting and challenging, as it needs proper channeling of electrons. In …

Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

PM Stanley, J Haimerl, NB Shustova, RA Fischer… - Nature Chemistry, 2022 - nature.com
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …

Enhanced photocatalytic CO2 reduction by integrating an iron based metal-organic framework and a photosensitizer

N Liu, K Tang, D Wang, F Fei, H Cui, F Li, J Lei… - Separation and …, 2024 - Elsevier
The conversion of CO 2 into fuels via photoreduction is a promising method to reduce
environmental pollution and alleviate the energy crisis. Herein, we report iron-based metal …

Thermally Induced Orderly Alignment of Porphyrin Photoactive Motifs in Metal–Organic Frameworks for Boosting Photocatalytic CO2 Reduction

ZW Huang, KQ Hu, XB Li, ZN Bin, QY Wu… - Journal of the …, 2023 - ACS Publications
Efficient transfer of charge carriers through a fast transport pathway is crucial to excellent
photocatalytic reduction performance in solar-driven CO2 reduction, but it is still challenging …

Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …