Electrochemical Manufacturing Routes for Organic Chemical Commodities

R Mathison, AL Ramos Figueroa… - Annual Review of …, 2023 - annualreviews.org
Electrochemical synthesis of organic chemical commodities provides an alternative to
conventional thermochemical manufacturing and enables the direct use of renewable …

Electrochemical Benzylic C(sp3)–H Acyloxylation

AP Atkins, AC Rowett, DM Heard, JA Tate… - Organic …, 2022 - ACS Publications
The development of sustainable C (sp3)–H functionalization methods is of great interest to
the pharmaceutical and agrochemical industries. Anodic oxidation is an efficient means of …

Alternating current electrolysis for individual synthesis of methanol and ethane from methane in a thermo-electrochemical cell

T Hibino, K Kobayashi, M Nagao, D Zhou, S Chen… - ACS …, 2023 - ACS Publications
The individual synthesis of methanol and ethane from methane was investigated using a
thermo-electrochemical cell in gas flow mode over the temperature range of 150–200° C …

Bio-electrocatalytic conversion of food waste to ethylene via succinic acid as the central intermediate

CM Pichler, S Bhattacharjee, E Lam, L Su… - ACS …, 2022 - ACS Publications
Ethylene is an important feedstock in the chemical industry, but currently requires production
from fossil resources. The electrocatalytic oxidative decarboxylation of succinic acid offers in …

Impact of Anodic Oxidation Reactions in the Performance Evaluation of High‐Rate CO2/CO Electrolysis

Q Xu, S Liu, F Longhin, G Kastlunger… - Advanced …, 2024 - Wiley Online Library
The membrane‐electrode assembly (MEA) approach appears to be the most promising
technique to realize the high‐rate CO2/CO electrolysis, however there are major challenges …

Study on the Effect of Electrolyte pH during Kolbe Electrolysis of Acetic Acid on Pt Anodes

MO Nordkamp, B Mei, R Venderbosch, G Mul - ChemCatChem, 2022 - Wiley Online Library
Kolbe already discovered in 1849 that electrochemical oxidative decarboxylation of
carboxylic acids is feasible and leads to formation of alkanes and CO2, via alkyl radical …

Competitive Valerate Binding Enables RuO2-Mediated Butene Electrosynthesis in Water

S Kunstelj, A Darù, A Sauza-de la Vega… - Journal of the …, 2024 - ACS Publications
The (non)-Kolbe oxidation of valeric acid, sourced from a hydrolysis product of cellulose,
provides a sustainable synthetic route to access value-added products, such as butene. An …

Accelerated analysis of the electrochemical production route for biomass-derived adiponitrile

R Mathison, E Rani, MK Patel, AL Cerrato… - Chem Catalysis, 2024 - cell.com
The electrochemical transformation of biomass feedstocks offers a promising route for the
sustainable production of fuels and chemicals, enhancing integration with renewable energy …

Electrochemical decarboxylation of acetic acid on boron-doped diamond and platinum-functionalised electrodes for pyrolysis-oil treatment

T Ashraf, AP Rodriguez, BT Mei, G Mul - Faraday Discussions, 2023 - pubs.rsc.org
Electrochemical decarboxylation of acetic acid on boron-doped-diamond (BDD) electrodes
was studied as a possible means to decrease the acidity of pyrolysis oil. It is shown that …

[HTML][HTML] Electrolyte dependence for the electrochemical decarboxylation of medium-chain fatty acids (n-octanoic acid) into fuel on Pt electrode

Z Zhang, D Ren, D Zhang, T Hu, C Zeng, N Xu… - Materials Reports …, 2024 - Elsevier
The deoxygenation of organic acids, important biomass feedstocks and derivatives, to
synthesize hydrocarbon products under mild electrochemical conditions, holds significant …