The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Nanographenes and graphene nanoribbons as multitalents of present and future materials science

Y Gu, Z Qiu, K Müllen - Journal of the American Chemical …, 2022 - ACS Publications
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …

Unraveling the structure and reactivity patterns of the indole radical cation in regioselective electrochemical oxidative annulations

X Liu, D Yang, Z Liu, Y Wang, Y Liu… - Journal of the …, 2023 - ACS Publications
Oxidation-induced strategy for inert chemical bond activation through highly active radical
cation intermediate has exhibited unique reactivity. Understanding the structure and …

Amplification of dissymmetry factors in π-extended [7]-and [9] helicenes

Z Qiu, CW Ju, L Frédéric, Y Hu… - Journal of the …, 2021 - ACS Publications
π-Extended helicenes constitute an important class of polycyclic aromatic hydrocarbons with
intrinsic chirality. Herein, we report the syntheses of π-extended [7] helicene 4 and π …

Small size, big impact: recent progress in bottom‐up synthesized nanographenes for optoelectronic and energy applications

Z Liu, S Fu, X Liu, A Narita, P Samorì, M Bonn… - Advanced …, 2022 - Wiley Online Library
Bottom‐up synthesized graphene nanostructures, including 0D graphene quantum dots and
1D graphene nanoribbons, have recently emerged as promising candidates for efficient …

Synthetic chiral molecular nanographenes: the key figure of the racemization barrier

JM Fernández-García, P Izquierdo-García… - Chemical …, 2022 - pubs.rsc.org
Chirality is one of the most intriguing concepts of chemistry, involving living systems and,
more recently, materials science. In particular, the bottom-up synthesis of molecular …

Synthesis of a Dicyclohepta[a,g]heptalene‐Containing Polycyclic Conjugated Hydrocarbon and the Impact of Non‐Alternant Topologies

J Wang, FG Gámez, J Marín‐Beloqui… - Angewandte …, 2023 - Wiley Online Library
Incorporating non‐hexagonal rings into polycyclic conjugated hydrocarbons (PCHs) can
significantly affect their electronic and optoelectronic properties and chemical reactivities …

Construction of heptagon‐containing molecular nanocarbons

Chaolumen, IA Stepek, KE Yamada… - Angewandte Chemie …, 2021 - Wiley Online Library
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …

Synthesis of highly luminescent chiral nanographene

JK Li, XY Chen, WL Zhao, YL Guo… - Angewandte Chemie …, 2023 - Wiley Online Library
Chiral nanographenes with both high fluorescence quantum yields (ΦF) and large
dissymmetry factors (glum) are essential to the development of circularly polarized …

Scholl reaction as a powerful tool for the synthesis of nanographenes: a systematic review

RS Jassas, EU Mughal, A Sadiq, RI Alsantali… - RSC …, 2021 - pubs.rsc.org
Nanographenes, or extended polycyclic aromatic hydrocarbons, have been attracting
increasing attention owing to their widespread applications in organic electronics. However …