Ligand-promoted palladium-catalyzed aerobic oxidation reactions
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …
application and extensive research efforts for nearly 60 years. A significant transition …
Versatile enantioselective synthesis of functionalized lactones via copper-catalyzed radical oxyfunctionalization of alkenes
R Zhu, SL Buchwald - Journal of the American Chemical Society, 2015 - ACS Publications
A versatile method for the rapid synthesis of diverse enantiomerically enriched lactones has
been developed based on Cu-catalyzed enantioselective radical oxyfunctionalization of …
been developed based on Cu-catalyzed enantioselective radical oxyfunctionalization of …
Direct annulations toward phosphorylated oxindoles: silver-catalyzed carbon-phosphorus functionalization of alkenes.
YM Li, M Sun, HL Wang, QP Tian… - Angewandte Chemie …, 2013 - search.ebscohost.com
Abstract Silver screen: The AgNO3‐catalyzed carbon phosphorylation of alkenes occurs by
an alkene addition/cyclization cascade. Ag+ reacts with Ph2P (O) H to form the crucial active …
an alkene addition/cyclization cascade. Ag+ reacts with Ph2P (O) H to form the crucial active …
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes
R Zhu, SL Buchwald - Journal of the American Chemical Society, 2012 - ACS Publications
A mild, versatile, and convenient method for the efficient oxytrifluoromethylation of
unactivated alkenes based on a copper-catalyzed oxidative difunctionalization strategy has …
unactivated alkenes based on a copper-catalyzed oxidative difunctionalization strategy has …
Ligand‐Enabled NiII‐Catalyzed Hydroxylarylation of Alkenes with Molecular Oxygen
DM Wang, LQ She, H Yuan, Y Wu… - Angewandte Chemie …, 2023 - Wiley Online Library
The use of molecular oxygen as the terminal oxidant in transition metal catalyzed oxidative
process is an appealing and challenging task in organic synthetic chemistry. Here, we report …
process is an appealing and challenging task in organic synthetic chemistry. Here, we report …
Synthesis of saturated heterocycles via metal-catalyzed alkene carboamination or carboalkoxylation reactions
JP Wolfe - Synthesis of Heterocycles via Metal-Catalyzed …, 2013 - Springer
This review describes recent advances over the past decade in the field of heterocycle
synthesis via Pd-catalyzed alkene carboamination or carboalkoxylation reactions. These …
synthesis via Pd-catalyzed alkene carboamination or carboalkoxylation reactions. These …
Copper-catalyzed intermolecular aminoazidation of alkenes
B Zhang, A Studer - Organic letters, 2014 - ACS Publications
Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel
methodology provides an efficient approach to vicinal amino azides which can easily be …
methodology provides an efficient approach to vicinal amino azides which can easily be …
Transition-metal-free oxyarylation of alkenes with aryl diazonium salts and TEMPONa
M Hartmann, Y Li, A Studer - Journal of the American Chemical …, 2012 - ACS Publications
The reaction of readily available TEMPONa with aryl diazonium salts allows for clean
generation of the corresponding aryl radicals along with TEMPO. Aryl radical addition to …
generation of the corresponding aryl radicals along with TEMPO. Aryl radical addition to …
Ligand-enabled gold-catalyzed 1, 2-heteroarylation of alkenes
By adopting the interplay between ligand-enabled Au (I)/Au (III) catalysis and the unique π-
activation mode of gold complexes, a highly coveted 1, 2-heteroarylation of alkenes has …
activation mode of gold complexes, a highly coveted 1, 2-heteroarylation of alkenes has …
Copper-catalyzed intramolecular alkene carboetherification: synthesis of fused-ring and bridged-ring tetrahydrofurans
Y Miller, L Miao, AS Hosseini… - Journal of the American …, 2012 - ACS Publications
Fused-ring and bridged-ring tetrahydrofuran scaffolds are found in a number of natural
products and biologically active compounds. A new copper-catalyzed intramolecular …
products and biologically active compounds. A new copper-catalyzed intramolecular …