Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …

Organic superbases are a distinct and increasingly utilized class of Brønsted base that
possess properties complementary to common inorganic bases. This Concept article …

Heteroatom-containing motifs are one of the most privileged scaffolds for pharmaceuticals,
agrochemicals, and functional materials. Transition-metal-catalyzed carbon–heteroatom …

This paper reports a photochemical C− N coupling of abundant, but less reactive aryl
chlorides, with structurally diverse primary and secondary amides by Ni‐mediated without …

The development of versatile methods for the formation of carbon‐nitrogen bonds has
significant impact on the synthetic chemistry community. However, it remains challenging …

Photochemistry enables new synthetic means to form carbon–heteroatom bonds.
Photocatalysts can catalyze carbon–heteroatom cross‐couplings by electron or energy …

This paper describes a mild strategy to promote amide arylations. Photoinduced oxidation of
a Ni (II) aryl amido intermediate is proposed to facilitate the challenging C–N reductive …

We report the use of dual nickel photocatalysis in the synthesis of O-aryl carbamates from
aryl iodides or bromides, amines, and carbon dioxide. The reaction proceeded in visible …

An efficient, convenient and novel method for the selective mono N-arylation of primary O-
alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids …