[HTML][HTML] Modelling and optimization of process variables for the solution polymerization of styrene using response surface methodology

RU Owolabi, MA Usman, AJ Kehinde - Journal of King Saud University …, 2018 - Elsevier
A satisfactory model for predicting monomer conversion in free radical polymerization has
been a challenge due to the complexity and rigors associated with classical kinetic models …

Simulation of radical polymerization of methyl methacrylate at room temperature using a tertiary amine/BPO initiating system

A Zoller, D Gigmes, Y Guillaneuf - Polymer Chemistry, 2015 - pubs.rsc.org
The decomposition kinetics of the initiation reaction between benzoyl peroxide and a tertiary
amine, either dimethyl-p-toluidine or dihydroxyethyl-p-toluidine, was studied by infrared …

Numerical investigations of perfectly mixed condition at the inlet of free radical polymerization tubular microreactors of different geometries

DK Garg, CA Serra, Y Hoarau, D Parida… - Macromolecular …, 2020 - Wiley Online Library
The numerical investigation of free radical polymerization (FRP) of methyl methacrylate
under mixed feed condition at inlet is made for three microtubular reactor geometries …

Toward the development of a mathematical model for the bulk in situ radical polymerization of methyl methacrylate in the presence of nano‐additives

GD Verros, DS Achilias - The Canadian Journal of Chemical …, 2016 - Wiley Online Library
The effect of nano‐additives on the radical polymerization kinetics of methyl methacrylate is
investigated through a simulation model. The mathematical model developed is based on …

Analytical solution of free radical polymerization: Applications-implementing gel effect using AK model

DK Garg, CA Serra, Y Hoarau, D Parida… - …, 2014 - ACS Publications
In this work, gel/glass/cage effects using the Achillias and Kiparissides (AK) model has been
incorporated in the analytical solution (AS) obtained in our previous work. The AK model is …

Autoacceleration in Bulk Free‐Radical Polymerization: Effect of Chain Transfer

D Victoria‐Valenzuela… - Macromolecular …, 2018 - Wiley Online Library
The model and methodology for estimating diffusion‐controlled rate coefficients for the
methyl methacrylate polymerization system reported in Parts I and II of this series is …

Analytical solutions for the rate equations of irreversible two-step consecutive processes with mixed second order later steps

G Lente - Journal of Mathematical Chemistry, 2017 - Springer
A general strategy was developed to solve the ordinary differential equations defined by two-
step chemical processes with a mixed second order later process for all possible cases of …

Analytical solutions for the rate equations of irreversible two-step consecutive processes with second order later steps

G Lente - Journal of Mathematical Chemistry, 2015 - Springer
Analytical solutions are presented for four consecutive two-step kinetic schemes, which
involve a first reaction with zeroth, first, second or mixed second order dependence and a …

Analytical solution of free radical polymerization: Applications-implementing gel effect using CCS model

DK Garg, CA Serra, Y Hoarau, D Parida… - …, 2014 - ACS Publications
This article presents the implementation of the Chiu, Carratt, and Soong (CCS) gel/glass
model in an analytical solution (AS) derived for the free radical polymerization under …

A detailed description of methyl methacrylate free radical polymerization using different heating policies under isothermal and non-isothermal conditions: a kinetic …

R Bairami Habashi, M Najafi, P Mostafaei… - International Journal of …, 2021 - Taylor & Francis
ABSTRACT A robust kinetic Monte Carlo (KMC) algorithm was precisely used to investigate
and monitor the bulk free radical polymerization of methyl methacrylate (MMA) employing …