Sulfoxides constitute one of the most important functional groups in organic chemistry found
in numerous pharmaceuticals and natural products. Sulfoxides are usually obtained from the …

Hypervalent iodine (V) derivatives such as 2‐iodoxybenzoic acid (IBX) and Dess–Martin
periodinane [DMP; 1, 1, 1‐tris (acetyloxy)‐1, 1‐dihydro‐1, 2‐benziodoxol‐3‐(1H)‐one] have …

Here we report a ternary catalyst system for the intramolecular hydroamidation of
unactivated olefins using simple N-aryl amide derivatives. Amide activation in these …

Chirality typically arises in molecules because of a rigidly chiral arrangement of covalently
bonded atoms. Less generally appreciated is that chirality can arise when molecules are …

Two new three-dimensional (3D) polyoxometalate-based metal–organic frameworks
(POMOFs),[M2 (btap) 4 (H2O) 4 (HPMo10VI Mo2VO40)](M= Co (1) and Cd (2); btap= 3, 5 …

The oxidation of sulfides to sulfoxides is of significant importance in organic chemistry, both
for fundamental research and for a wide range of applications. The synthesis of sulfoxides …

In the past decade, the chemistry of hypervalent iodine compounds (l3-and l5-iodanes) has
experienced an unprecedented growth. 1 Large atomic size and low ionization potential …

Mesoporous graphitic carbon nitride (mpg-C3N4) has been developed as a non-metal,
heterogeneous photocatalyst for the selective oxidation of sulfides to sulfoxides with O2 at …

Radical thiol–yne coupling (TYC) has emerged as one of the most appealing click chemistry
procedures, appearing as a sound candidate for replacing/complementing other popular …

Tetra-(tetraalkylammonium) octamolybdate catalysts are successfully applied in the
selective oxidation of various sulfides to sulfoxides with 30% aqueous hydrogen peroxide as …