Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
Owing to the vast diversity of linkers, nodes, and topologies, metal–organic frameworks can
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …
Metal organic frameworks mimicking natural enzymes: a structural and functional analogy
I Nath, J Chakraborty, F Verpoort - Chemical Society Reviews, 2016 - pubs.rsc.org
In this review, we have portrayed the structure, synthesis and applications of a variety of
biomimetic MOFs from an unprecedented angle. Synthetic MOF analogues of five distinct …
biomimetic MOFs from an unprecedented angle. Synthetic MOF analogues of five distinct …
Zirconium-based metal–organic frameworks for the catalytic hydrolysis of organophosphorus nerve agents
Organophoshorus nerve agents are among the most toxic chemicals known to humans, and
because of their unfortunate recent use despite international bans, there is an urgent need …
because of their unfortunate recent use despite international bans, there is an urgent need …
Acetylcholinesterase inhibitors: pharmacology and toxicology
MB Colovic, DZ Krstic… - Current …, 2013 - ingentaconnect.com
Acetylcholinesterase is involved in the termination of impulse transmission by rapid
hydrolysis of the neurotransmitter acetylcholine in numerous cholinergic pathways in the …
hydrolysis of the neurotransmitter acetylcholine in numerous cholinergic pathways in the …
Evaluating pesticide degradation in the environment: blind spots and emerging opportunities
K Fenner, S Canonica, LP Wackett, M Elsner - science, 2013 - science.org
The benefits of global pesticide use come at the cost of their widespread occurrence in the
environment. An array of abiotic and biotic transformations effectively removes pesticides …
environment. An array of abiotic and biotic transformations effectively removes pesticides …
Fibrous Zr‐MOF Nanozyme Aerogels with Macro‐Nanoporous Structure for Enhanced Catalytic Hydrolysis of Organophosphate Toxins
Metal–organic frameworks (MOFs) with Lewis acid catalytic sites, such as zirconium‐based
MOFs (Zr‐MOFs), comprise a growing class of phosphatase‐like nanozymes that can …
MOFs (Zr‐MOFs), comprise a growing class of phosphatase‐like nanozymes that can …
Instantaneous hydrolysis of nerve‐agent simulants with a six‐connected zirconium‐based metal–organic framework
A nerve‐agent simulant based on a phosphate ester is hydrolyzed using a MOF‐based
catalyst. Suspensions of MOF‐808 (6‐connected), a material featuring 6‐connected …
catalyst. Suspensions of MOF‐808 (6‐connected), a material featuring 6‐connected …
Ultrahigh-throughput discovery of promiscuous enzymes by picodroplet functional metagenomics
Unculturable bacterial communities provide a rich source of biocatalysts, but their
experimental discovery by functional metagenomics is difficult, because the odds are …
experimental discovery by functional metagenomics is difficult, because the odds are …
Catalytic degradation of chemical warfare agents and their simulants by metal-organic frameworks
Since sulfur mustard was first used in World War I, significant efforts have been made in
materials and methods development for the adsorption and detoxification of different classes …
materials and methods development for the adsorption and detoxification of different classes …
Quantum chemical studies of mechanisms for metalloenzymes
Two decades ago, theoretical model calculations played a truly minor role in understanding
mechanisms of redox-active metalloenzymes. The methods available to treat transition …
mechanisms of redox-active metalloenzymes. The methods available to treat transition …