Asymmetric synthesis of P-stereogenic phosphindane oxides via kinetic resolution and their biological activity

L Yin, J Li, C Wu, H Zhang, W Zhao, Z Fan… - Nature …, 2024 - nature.com
The importance of P-stereogenic heterocycles has been widely recognized with their
extensive use as privileged chiral ligands and bioactive compounds. The catalytic …

Remote Enantioselective Epoxidation Reactions Catalyzed by Chiral Iron Porphyrin Complexes with a Hydrogen-Bonding Site

H Ahmed, A Pöthig, KN Truong, T Bach - Synlett, 2024 - thieme-connect.com
Iron porphyrin complexes, which were linked via a para-phenylethynyl group to a chiral
scaffold with a lactam binding site, were probed as catalysts in the enantioselective …

HCat-GNet: An Interpretable Graph Neural Network for Catalysis Optimization

EAA Bejarano, G Figueredo, S Woodward, HW Lam… - 2024 - chemrxiv.org
Homogeneous catalysts enable faster conversions of molecules with higher selectivities
(stereo-and regioselectivity) in chemical reactions. Traditionally, catalyst improvements are …