Toolbox for distal C–H bond functionalizations in organic molecules
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
Visible‐light photocatalysis: does it make a difference in organic synthesis?
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …
organic synthesis. Photocatalytic variants have been reported for many important …
Controlling Ni redox states by dynamic ligand exchange for electroreductive Csp3–Csp2 coupling
TB Hamby, MJ LaLama, CS Sevov - Science, 2022 - science.org
Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but
limited to specific substrate classes. Here, we report electroreductive XEC of previously …
limited to specific substrate classes. Here, we report electroreductive XEC of previously …
Controlling Reactivity and Selectivity in the Nondirected C–H Activation of Arenes with Palladium
S Kaltenberger, M van Gemmeren - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Aromatic structures are widespread motifs throughout organic chemistry, and C–
H activation has been recognized as a major tool for enabling their sustainable and efficient …
H activation has been recognized as a major tool for enabling their sustainable and efficient …
Modern transition-metal-catalyzed carbon–halogen bond formation
The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …
number of transformations which install the carbon–halogen motif. Traditional routes to …
Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …
Beyond Directing Groups: Transition‐Metal‐Catalyzed C H Activation of Simple Arenes
N Kuhl, MN Hopkinson… - Angewandte Chemie …, 2012 - Wiley Online Library
The use of coordinating moieties as directing groups for the functionalization of aromatic C
H bonds has become an established tool to enhance reactivity and induce regioselectivity …
H bonds has become an established tool to enhance reactivity and induce regioselectivity …
DMSO-catalysed late-stage chlorination of (hetero) arenes
The chlorination of a bioactive compound can change its physiological properties and
improve its pharmacokinetic and pharmacological profiles. It therefore has been an …
improve its pharmacokinetic and pharmacological profiles. It therefore has been an …
Arene‐Limited Nondirected C− H Activation of Arenes
P Wedi, M van Gemmeren - Angewandte Chemie International …, 2018 - Wiley Online Library
Abstract The nondirected C (sp2)− H activation of simple arenes has advanced significantly
in recent years through the discovery of new catalyst systems that are able to perform …
in recent years through the discovery of new catalyst systems that are able to perform …
Ohne dirigierende gruppen: übergangsmetallkatalysierte C‐H‐Aktivierung einfacher Arene
N Kuhl, MN Hopkinson, J Wencel‐Delord… - Angewandte …, 2012 - Wiley Online Library
Abstract Der Einsatz von koordinierenden Gruppen als dirigierende Gruppen ist eine
zuverlässige Methode zur Kontrolle von Reaktivität und Selektivität bei der Aktivierung von …
zuverlässige Methode zur Kontrolle von Reaktivität und Selektivität bei der Aktivierung von …