Enzymes containing molybdenum or tungsten at their active sites appear to be present in all
forms of life, from ancient archaea to man. These enzymes catalyze a wide range of …

▪ Abstract Metallocluster-containing enzymes catalyze some of the most basic redox
transformations in the biosphere. The reactions catalyzed by these enzymes typically involve …

We report a class of molecules with extremely low ionization enthalpies, one member of
which has been determined to have a gas-phase ionization energy (onset, 3.51 electron …

A series of dithiolene complexes of the general type [MoIV (QR ')(S2C2Me2) 2] 1-has been
prepared and structurally characterized as possible structural and reactivity analogues of …

Solution and solid state electronic absorption, magnetic circular dichroism, and resonance
Raman spectroscopies have been used to probe in detail the excited state electronic …

The pteridine and (iso) alloxazine π systems are the underlying heterocyclic structures of
coenzymatic constituents (pterins, lumazines, flavins) of oxidoreductase enzymes. These …

In this work, native cellulose cotton fibers were first modified through graft copolymerization
of polyacrylonitrile (PAN) and then by insertion of phenyl thiosemicarbazide moieties to …

Gas-phase photoelectron spectroscopy and density functional theory have been used to
investigate the interactions between the sulfur π-orbitals of arene dithiolates and high-valent …

This chapter provides a detailed description of the electronic structure and spectroscopy of
metallo‐dithiolene complexes, which play key roles in bioinorganic chemistry and materials …

A fast and selective adsorbent for Hg (II) from aqueous solutions using thiourea (TU)
functionalized polypropylene fiber grafted acrylic acid (PP-g-AA), PP-g-AA-TU fibers, was …