Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Single-chain magnets: beyond the Glauber model

WX Zhang, R Ishikawa, B Breedlove, M Yamashita - RSC advances, 2013 - pubs.rsc.org
Single-chain magnets (SCMs) are one-dimensional (1D) slow-relaxing magnetic chains with
interesting fundamental properties and applications, such as information storage. The …

Zinc–organic battery with a wide operation‐temperature window from− 70 to 150° C

N Wang, X Dong, B Wang, Z Guo… - Angewandte Chemie …, 2020 - Wiley Online Library
Aqueous zinc (Zn) batteries have been considered as promising candidates for grid‐scale
energy storage. However, their cycle stability is generally limited by the structure collapse of …

Nanoporous cobalt (II) MOF exhibiting four magnetic ground states and changes in gas sorption upon post-synthetic modification

MH Zeng, Z Yin, YX Tan, WX Zhang… - Journal of the …, 2014 - ACS Publications
We present the syntheses, structural characterization, gas sorption, I2 uptake, and magnetic
properties of a double-walled porous metal–organic framework,[CoII3 (lac) 2 (pybz) 2] …

Field-induced slow magnetic relaxation in a six-coordinate mononuclear cobalt (II) complex with a positive anisotropy

J Vallejo, I Castro, R Ruiz-García, J Cano… - Journal of the …, 2012 - ACS Publications
The novel mononuclear Co (II) complex cis-[CoII (dmphen) 2 (NCS) 2]· 0.25 EtOH
(1)(dmphen= 2, 9-dimethyl-1, 10-phenanthroline) features a highly rhombically distorted …

[HTML][HTML] Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Single‐chain magnet based on cobalt (II) thiocyanate as XXZ spin chain

M Rams, A Jochim, M Böhme… - … A European Journal, 2020 - Wiley Online Library
The cobalt (II) in [Co (NCS) 2 (4‐methoxypyridine) 2] n are linked by pairs of thiocyanate
anions into linear chains. In contrast to a previous structure determination, two …

Enhanced Single‐Chain Magnet Behavior via Anisotropic Exchange in a Cyano‐Bridged MoIII–MnII Chain

L Shi, D Shao, XQ Wei, KR Dunbar… - Angewandte Chemie …, 2020 - Wiley Online Library
Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …

[ReF6]2−: A Robust Module for the Design of Molecule‐Based Magnetic Materials

KS Pedersen, M Sigrist, MA Sørensen… - Angewandte Chemie …, 2014 - Wiley Online Library
A facile synthesis of the [ReF6] 2− ion and its use as a building block to synthesize magnetic
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …

Structural and magnetic properties of some lanthanide (Ln= Eu (III), Gd (III) and Nd (III)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and …

A Arauzo, A Lazarescu, S Shova, E Bartolomé… - Dalton …, 2014 - pubs.rsc.org
The lanthanide (III) cyanoacetate complexes of the formula {[Ln2 (CNCH2COO) 6 (H2O) 4]·
2H2O} n, where Ln= Eu (1), Gd (2), Nd (3), have been prepared and characterized by X-ray …