Chirality sensing using stereodynamic probes with distinct electronic circular dichroism output
C Wolf, KW Bentley - Chemical Society Reviews, 2013 - pubs.rsc.org
Circular dichroism (CD) spectroscopy is one of the most useful techniques for the
stereochemical analysis of chiral biopolymers and fine chemicals. It has become invaluable …
stereochemical analysis of chiral biopolymers and fine chemicals. It has become invaluable …
Circular dichroism sensing: Strategies and applications
JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …
chiral compounds are frequently encountered tasks across the chemical and health …
Recent progress on the stereoselective synthesis of cyclic quaternary α-amino acids
C Cativiela, M Ordóñez - Tetrahedron: Asymmetry, 2009 - Elsevier
The most recent papers describing the stereoselective synthesis of cyclic quaternary α-
amino acids are collected in this review. The diverse synthetic approaches are classified …
amino acids are collected in this review. The diverse synthetic approaches are classified …
Flexible biphenyl chromophore as a circular dichroism probe for assignment of the absolute configuration of carboxylic acids
S Superchi, R Bisaccia, D Casarini… - Journal of the …, 2006 - ACS Publications
A general and nonempirical approach to determine the absolute configuration (AC) of 2-
substituted chiral carboxylic acids by circular dichroism (CD) spectroscopy has been …
substituted chiral carboxylic acids by circular dichroism (CD) spectroscopy has been …
Helical screw‐sense preferences of peptides based on chiral, Cα‐tetrasubstituted α‐amino acids
M Crisma, C Toniolo - Peptide Science, 2015 - Wiley Online Library
The preferred helical screw senses of chiral α‐amino acids with a Cα‐tetrasubstituted α‐
carbon atom, as determined in the crystal state by X‐ray diffraction analyses on derivatives …
carbon atom, as determined in the crystal state by X‐ray diffraction analyses on derivatives …
Practical methods for the synthesis of symmetrically α, α-disubstituted α-amino acids
VA Soloshonok, AE Sorochinsky - Synthesis, 2010 - thieme-connect.com
This report provides an overview of the practical methods for preparing symmetrically α, α-
disubstituted α-amino acids and their derivatives. Despite the growing application of this …
disubstituted α-amino acids and their derivatives. Despite the growing application of this …
Substrate‐Specific Amino Acid Sensing Using a Molecular d/ l‐Cysteine Probe for Comprehensive Stereochemical Analysis in Aqueous Solution
FY Thanzeel, C Wolf - Angewandte Chemie International …, 2017 - Wiley Online Library
The appearance of d‐amino acids in mammals and humans has important implications in
the life sciences. d/l‐Amino acid mixtures play a key role in human physiology and …
the life sciences. d/l‐Amino acid mixtures play a key role in human physiology and …
A stereodynamic probe providing a chiroptical response to substrate-controlled induction of an axially chiral arylacetylene framework
DP Iwaniuk, C Wolf - Journal of the American Chemical Society, 2011 - ACS Publications
A stereodynamic probe containing a central 1, 4-di (phenylethynyl) benzene rod and two 2-
formylphenylethynyl branches has been prepared through a series of Sonogashira cross …
formylphenylethynyl branches has been prepared through a series of Sonogashira cross …
The Bip method, based on the induced circular dichroism of a flexible biphenyl probe in terminally protected-Bip-Xaa*-dipeptides, for assignment of the absolute …
L Dutot, K Wright, A Gaucher… - Journal of the …, 2008 - ACS Publications
An induced axial chirality of the biphenyl core of the Bip (2′, 1′: 1, 2; 1′′, 2′′: 3, 4-
dibenzcyclohepta-1, 3-diene-6-amino-6-carboxylic acid) residue in the terminally protected …
dibenzcyclohepta-1, 3-diene-6-amino-6-carboxylic acid) residue in the terminally protected …
Dynamic molecular propeller: supramolecular chirality sensing by enhanced chiroptical response through the transmission of point chirality to mobile helicity
R Katoono, H Kawai, K Fujiwara… - Journal of the American …, 2009 - ACS Publications
The secondary terephthalamide host 1a-H attached to four aryl blades was prepared from
tetrabromide 2a by Suzuki− Miyaura coupling and undergoes a conformational change from …
tetrabromide 2a by Suzuki− Miyaura coupling and undergoes a conformational change from …