Specific countermeasures to intrinsic capacity decline issues and future direction of LiMn2O4 cathode

X Hou, X Liu, H Wang, X Zhang, J Zhou… - Energy Storage Materials, 2023 - Elsevier
Spinel LiMn 2 O 4 cathodes are particularly attractive in lithium-ion batteries (LIBs) owing to
the nontoxic Mn sources, abundant reserves, and high specific power. However, poor …

High-voltage positive electrode materials for lithium-ion batteries

W Li, B Song, A Manthiram - Chemical Society Reviews, 2017 - pubs.rsc.org
The ever-growing demand for advanced rechargeable lithium-ion batteries in portable
electronics and electric vehicles has spurred intensive research efforts over the past decade …

Chemical, structural, and electronic aspects of formation and degradation behavior on different length scales of Ni‐rich NCM and Li‐rich HE‐NCM cathode materials …

L de Biasi, B Schwarz, T Brezesinski… - Advanced …, 2019 - Wiley Online Library
In order to satisfy the energy demands of the electromobility market, both Ni‐rich and Li‐rich
layered oxides of NCM type are receiving much attention as high‐energy‐density cathode …

Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries

S Hy, H Liu, M Zhang, D Qian, BJ Hwang… - Energy & Environmental …, 2016 - pubs.rsc.org
The Li-excess oxide compound is one of the most promising positive electrode materials for
next generation batteries exhibiting high capacities of> 300 mA hg− 1 due to the …

Fundamental understanding and practical challenges of lithium-rich oxide cathode materials: Layered and disordered-rocksalt structure

Y Fan, W Zhang, Y Zhao, Z Guo, Q Cai - Energy Storage Materials, 2021 - Elsevier
Lithium-rich oxides have been considered as one of the most promising cathode materials
for lithium-ion batteries due to the competitively high specific capacity contributed by both …

Lithium Extraction Mechanism in Li-Rich Li2MnO3 Involving Oxygen Hole Formation and Dimerization

H Chen, MS Islam - Chemistry of Materials, 2016 - ACS Publications
Lithium-rich oxide electrodes with layered structures have attracted considerable interest
because they can deliver high energy densities for lithium-ion batteries. However, there is …

Quantifying the Capacity Contributions during Activation of Li2MnO3

J Rana, JK Papp, Z Lebens-Higgins, M Zuba… - ACS Energy …, 2020 - ACS Publications
Though Li2MnO3 was originally considered to be electrochemically inert, its observed
activation has spawned a new class of Li-rich layered compounds that deliver capacities …

Reaction inhomogeneity coupling with metal rearrangement triggers electrochemical degradation in lithium-rich layered cathode

L Wang, T Liu, A Dai, V De Andrade, Y Ren… - Nature …, 2021 - nature.com
High-energy density lithium-rich layered oxides are among the most promising candidates
for next-generation energy storage. Unfortunately, these materials suffer from severe …

Molecular orbital principles of oxygen-redox battery electrodes

M Okubo, A Yamada - ACS applied materials & interfaces, 2017 - ACS Publications
Lithium-ion batteries are key energy-storage devices for a sustainable society. The most
widely used positive electrode materials are Li M O2 (M: transition metal), in which a redox …

Review of spinel LiMn2O4 cathode materials under high cut-off voltage in lithium-ion batteries: Challenges and strategies

ZI Radzi, KH Arifin, MZ Kufian, V Balakrishnan… - Journal of …, 2022 - Elsevier
The growing demand for high energy and power density in lithium-ion batteries mandates
the utilization of cathode material with improved capacity and output voltage. Among various …