Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols
The synthesis of heterocycles is an emerging area of chemical research considering their
high importance in pharmaceuticals, material chemistry, and natural product synthesis. The …
high importance in pharmaceuticals, material chemistry, and natural product synthesis. The …
Cobalt-catalyzed dehydrogenative functionalization of alcohols: progress and future prospect
Functionalization of alcohol is a promising field in synthesis for the possible conservation of
fossil-based-feedstocks, since alcohols can be easily obtained from readily available …
fossil-based-feedstocks, since alcohols can be easily obtained from readily available …
Borrowing Hydrogen β-Phosphinomethylation of Alcohols Using Methanol as C1 Source by Pincer Manganese Complex
F Sun, X Chen, S Wang, F Sun… - Journal of the American …, 2023 - ACS Publications
Herein, we report a manganese-catalyzed three-component coupling of β-H containing
alcohols, methanol, and phosphines for the synthesis of γ-hydroxy phosphines via a …
alcohols, methanol, and phosphines for the synthesis of γ-hydroxy phosphines via a …
Multifunctional catalysis of nanosheet defective molybdenum sulfide basal planes for tandem reactions involving alcohols and molecular hydrogen
M Rodenes, F Dhaeyere, S Martín… - ACS Sustainable …, 2023 - ACS Publications
Establishing tandem catalytic synthetic strategies based on the use of readily available,
stable, and renewable feedstocks is of great significant for the sustainable advancement of …
stable, and renewable feedstocks is of great significant for the sustainable advancement of …
Dehydrogenative synthesis of quinolines and quinazolines via ligand-free cobalt-catalyzed cyclization of 2-aminoaryl alcohols with ketones or nitriles
Z Hao, X Zhou, Z Ma, C Zhang, Z Han… - The Journal of Organic …, 2022 - ACS Publications
We present a convenient and efficient protocol to synthesize quinolines and quinazolines in
one pot under mild conditions. A variety of substituted quinolines were synthesized in good …
one pot under mild conditions. A variety of substituted quinolines were synthesized in good …
Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N‐Heterocycles: A Comparison between Base and Noble Metal …
N Hofmann, KC Hultzsch - European Journal of Organic …, 2021 - Wiley Online Library
Acceptorless dehydrogenative coupling reactions (ADC) and hydrogen transfer strategies
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
Manganese (I)-catalyzed sustainable synthesis of quinoxaline and quinazoline derivatives with the liberation of dihydrogen
Direct synthesis of N-heterocycles via the acceptorless dehydrogenative coupling is very
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …
Novel methodologies for chemical activation in organic synthesis under solvent-free reaction conditions
CG Avila-Ortiz, E Juaristi - Molecules, 2020 - mdpi.com
One central challenge for XXI century chemists is the development of sustainable processes
that do not represent a risk either to humanity or to the environment. In this regard, the …
that do not represent a risk either to humanity or to the environment. In this regard, the …
Simple RuCl3‐catalyzed N‐Methylation of Amines and Transfer Hydrogenation of Nitroarenes using Methanol
Methanol is a potential hydrogen source and C1 synthon, which finds interesting
applications in both chemical synthesis and energy technologies. The effective utilization of …
applications in both chemical synthesis and energy technologies. The effective utilization of …
Ruthenium Pincer Complex Catalyzed Selective Synthesis of C‐3 Alkylated Indoles and Bisindolylmethanes Directly from Indoles and Alcohols
Herein, we presented Ru‐SNS complex that serves as a useful catalyst for C‐3 alkylation of
1H‐indoles with various aliphatic primary and secondary alcohols including cyclic alcohols …
1H‐indoles with various aliphatic primary and secondary alcohols including cyclic alcohols …