Reaction of acyl chlorides with organometallic reagents: A banquet table of metals for ketone synthesis

RK Dieter - Tetrahedron, 1999 - Elsevier
The synthesis of ketones from carboxylic acids or their derivatives is an important synthetic
operation whereby CC bond construction and functional group interconversion is achieved …

Organocopper reagents: substitution, conjugate addition, carbo/metallocupration, and other reactions

BH Lipshutz, S Sengupta - Organic Reactions, 2004 - Wiley Online Library
Well over a decade ago, two reviews were contributed to the Organic Reactions series
covering substitution and conjugate addition reactions in organocopper chemistry. Their …

Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes

E Shirakawa, T Yamagami, T Kimura… - Journal of the …, 2005 - ACS Publications
Arylmagnesiation of Alkynes Catalyzed Cooperatively by Iron and Copper Complexes | Journal
of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log …

Cyanocuprates convert carboxylic acids directly into ketones

DT Genna, GH Posner - Organic Letters, 2011 - ACS Publications
Carboxylic acids were converted directly in 56–99% yields into methyl, n-butyl, and
isopropyl ketones using excess cyanocuprates R2CuLi· LiCN. A substrate with a …

Conjugate addition of lithiated methyl pyridines to enones

DF Taber, P Guo, MT Pirnot - The Journal of organic chemistry, 2010 - ACS Publications
Conjugate Addition of Lithiated Methyl Pyridines to Enones | The Journal of Organic
Chemistry ACS ACS Publications C&EN CAS Find my institution Log In The Journal of …

Efficient generation and trapping of acylbenzynes from hypervalent iodine compounds

T Kitamura, Y Aoki, S Isshiki, K Wasai, Y Fujiwara - Tetrahedron letters, 2006 - Elsevier
[5-Acyl-2-(trimethylsilyl) phenyl] iodonium triflates were prepared for the generation of
benzynes bearing ketone function. Treatment of the iodonium triflates with Bu4NF in CH2Cl2 …

Concerning the solution composition of the normant reagent. New THF soluble methyl copper (I) ate complexes by reaction of “CH3MgBr” and (CH3) 2Mg with …

EC Ashby, AB Goel, RS Smith - Journal of Organometallic Chemistry, 1981 - Elsevier
Preliminary communication CONCERNING THE SOLUTION COMPOSITION OF THE
NORMANT REAGENT_ NEW THF SOLUBLE METHYL COPPER(I) COMPLEXES Page 1 c47 …

The reaction of the phenyl-copper-magnesium reagent, prepared from 2 PhMgBr and CuI, with some organic halides

MT Rahman, SK Nahar - Journal of organometallic chemistry, 1980 - Elsevier
The reagent prepared from 2 PhMgBr and CuI reacts with allyl and benzyl bromides to give
allylbenzene and diphenylmethane, respectively, in 52 and 62% yields. The yields rise to 82 …

Preparations and selectivities of magnesium-based mixed cuprates

SMH Kabir, MT Rahman - Journal of Organometallic Chemistry, 2001 - Elsevier
The reactions of magnesium-based cuprates 'R2CuMg'(prepared from 2RMgX+ CuI) with
methyl cinnamate furnish conjugate addition products in 60–82% yields. The mixed cuprates …

The reaction of arylcoppermagnesium and other organometallic reagents with phthalic anhydride

MT Rahman, SK Nahar - Journal of organometallic chemistry, 1992 - Elsevier
Arylcoppermagnesium reagents, prepared from 5ArMgX+ 2.5 CuI,(Ar= 4-CH 3 C 6 H 4, 4-CH
3 OC 6 H 4, 4-ClC 6 H 4, 2-C 4 H 3 S react with one equivalent of phthalic anhydride in ether …