Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Hydrazone based spin crossover complexes: Behind the extra flexibility of the hydrazone moiety to switch the spin state

T Gebretsadik, Q Yang, J Wu, J Tang - Coordination Chemistry Reviews, 2021 - Elsevier
Recently, ligand systems with straightforward synthesis, easily tunable and better stability
are becoming an attractive research area in coordination chemistry where hydrazone based …

Crystal-liquid-glass transition and near-unity photoluminescence quantum yield in low melting point hybrid metal halides

Y Zhang, Y Zhang, Y Zhao, H Jia, Z Yang… - Journal of the …, 2023 - ACS Publications
Hybrid metal halides (HMHs) are a class of materials that combine extraordinary
photophysical properties and excellent processability. Their chemical variability allows for …

105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism

M Seredyuk, K Znovjyak… - Journal of the …, 2022 - ACS Publications
Little is known about the mechanisms behind the bistability (memory) of molecular spin
transition compounds over broad temperature ranges (> 100 K). To address this point, we …

Rhodamine 6G-labeled pyridyl aroylhydrazone Fe (II) complex exhibiting synergetic spin crossover and fluorescence

J Yuan, SQ Wu, MJ Liu, O Sato… - Journal of the American …, 2018 - ACS Publications
Here, we use a pyridinecarbaldehyde rhodamine 6G hydrazone ligand (L) to synthesize an
Fe (II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single …

Complete set of elastic moduli of a spin-crossover solid: Spin-state dependence and mechanical actuation

M Mikolasek, MD Manrique-Juarez… - Journal of the …, 2018 - ACS Publications
Molecular spin crossover complexes are promising candidates for mechanical actuation
purposes. The relationships between their crystal structure and mechanical properties …

Multistability at room temperature in a bent-shaped spin-crossover complex decorated with long alkyl chains

D Rosario-Amorin, P Dechambenoit… - Journal of the …, 2018 - ACS Publications
An iron (II) pyridyl-benzohydrazonate-based complex decorated with long alkyl chains is
reported as a rare spin-crossover compound displaying a wide thermal hysteresis spanning …

Thermochromic meltable materials with reverse spin transition controlled by chemical design

FJ Valverde‐Muñoz, M Seredyuk… - Angewandte …, 2020 - Wiley Online Library
We report a series of meltable FeII complexes, which, depending on the length of aliphatic
chains, display abrupt forward low‐spin to high‐spin transition or unprecedented melting …

Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron (II) incorporating tetrathiafulvalene

YR Qiu, L Cui, PY Cai, F Yu, M Kurmoo, CF Leong… - Chemical …, 2020 - pubs.rsc.org
In designing multifunctional materials for potential switches that can be used as memory
devices, the high-spin (HS) to low-spin (LS) crossover (SCO) one-dimensional polymer,[FeII …

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

FJ Valverde-Muñoz, M Seredyuk… - Chemical …, 2019 - pubs.rsc.org
A multistable spin crossover (SCO) molecular alloy system [Fe1− xMx (nBu-im) 3 (tren)](P1−
yAsyF6) 2 (M= ZnII, NiII;(nBu-im) 3 (tren)= tris (n-butyl-imidazol (2-ethylamino)) amine) has …