Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides
have become a steadily growing field in organometallic chemistry. The predominant part of …

The synthesis and study of radioactive compounds are both inherently limited by their
toxicity, cost and isotope scarcity. Traditional methods using small inorganic or organic …

Complexes of the form [U (η6-arene)(BH4) 3] where arene= C6H6; C6H5Me; C6H3-1, 3, 5-
R3 (R= Et, iPr, tBu, Ph); C6Me6; and triphenylene (C6H4) 3 were investigated towards an …

Lanthanide rare-earth metals are ubiquitous in modern technologies,,,–, but we know little
about chemistry of the 61st element, promethium (Pm), a lanthanide that is highly radioactive …

Comparison of bonding and electronic structural features between trivalent lanthanide (Ln)
and actinide (An) complexes across homologous series' of molecules can provide insights …

Early-actinide-based (U, Np, and Pu) single-molecule magnets (SMMs) have yet to show
magnetic properties similar to those of highly anisotropic lanthanide-based ones. However …

Dinuclear, organometallic, transuranium compounds,(Cp′ 3M) 2 (μ-4, 4′-bpy)(Cp′–=
trimethylsilylcyclopentadienide, 4, 4′-bpy= 4, 4′-bipyridine, M= Ce, Np, Pu), reported …

Structural and electronic characterization of (Cp′ 3Cm) 2 (μ− 4, 4′− bpy)(Cp′=
trimethylsilylcyclopentadienyl, 4, 4′− bpy= 4, 4′− bipyridine) is reported and provides a …

Despite the availability of transuranic elements increasing in recent years, our
understanding of their most basic and inherent radiation chemistry is limited and yet …

Deciphering the solution chemistry and speciation of actinides is inherently difficult due to
radioactivity, rarity, and cost constraints, especially for transplutonium elements. In this …