Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures
XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …
[HTML][HTML] Metal–metal bond in lanthanide single-molecule magnets
Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
[HTML][HTML] TURBOMOLE: Modular program suite for ab initio quantum-chemical and condensed-matter simulations
TURBOMOLE is a collaborative, multi-national software development project aiming to
provide highly efficient and stable computational tools for quantum chemical simulations of …
provide highly efficient and stable computational tools for quantum chemical simulations of …
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …
size limit for molecule-based magnetic information storage materials. Their current drawback …
A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …
them at the forefront of the race toward high-temperature single-molecule magnets and …
Strong axiality in a dysprosium (III) bis (borolide) complex leads to magnetic blocking at 65 K
AH Vincent, YL Whyatt, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …
[HTML][HTML] Symmetry strategies for high performance lanthanide-based single-molecule magnets
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
Recent advances in crystalline hybrid photochromic materials driven by electron transfer
SD Han, JX Hu, GM Wang - Coordination Chemistry Reviews, 2022 - Elsevier
Photochromic materials have broad application prospects in the fields of molecular
switching, detection, biological, and molecular machines. Crystalline hybrid photochromic …
switching, detection, biological, and molecular machines. Crystalline hybrid photochromic …
[HTML][HTML] High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
A dysprosium metallocene single‐molecule magnet functioning at the axial limit
Abstraction of a chloride ligand from the dysprosium metallocene [(Cpttt) 2DyCl](1Dy Cpttt=
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …