Carbenes: Synthesis, properties, and organometallic chemistry
P De Fremont, N Marion, SP Nolan - Coordination Chemistry Reviews, 2009 - Elsevier
Carbenes, thought of only as transient species for a long time, have become ubiquitous in
organometallic chemistry. Their interaction with a metal center, which allows for their …
organometallic chemistry. Their interaction with a metal center, which allows for their …
Molecular double‐bond covalent radii for elements Li–E112
P Pyykkö, M Atsumi - Chemistry–A European Journal, 2009 - Wiley Online Library
The previous systems of triple‐bond and single‐bond self‐consistent, additive covalent radii,
R (AB)= r (A)+ r (B), are completed with a fit for σ2π2 double‐bonds. The primary bond …
R (AB)= r (A)+ r (B), are completed with a fit for σ2π2 double‐bonds. The primary bond …
Matrix preparation and spectroscopic and theoretical investigation of small high oxidation-state complexes of groups 3–12, 14, lanthanide and actinide metal atoms …
HG Cho, L Andrews - Coordination Chemistry Reviews, 2017 - Elsevier
Our first review article in 2006 outlined the observation, photochemical properties, and
theoretical investigations of a new breed of small transition-metal complexes with CM …
theoretical investigations of a new breed of small transition-metal complexes with CM …
Matrix Preparation and Spectroscopic and Theoretical Investigations of Simple Methylidene and Methylidyne Complexes of Group 4− 6 Transition Metals
L Andrews, HG Cho - Organometallics, 2006 - ACS Publications
A new generation of simple methylidene complexes has been prepared by reactions of
excited group 4− 6 transition metal atoms with methyl halides and methane in solid argon …
excited group 4− 6 transition metal atoms with methyl halides and methane in solid argon …
[HTML][HTML] Synthesis and electronic structure analysis of the actinide allenylidenes,[{(NR 2) 3} An (CCCPh 2)]−(An= U, Th; R= SiMe 3)
GT Kent, X Yu, G Wu, J Autschbach, TW Hayton - Chemical Science, 2021 - pubs.rsc.org
The reaction of [AnCl (NR2) 3](An= U, Th, R= SiMe3) with in situ generated lithium-3, 3-
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium
DE Smiles, G Wu, P Hrobárik, TW Hayton - Organometallics, 2017 - ACS Publications
Reaction of the Th (IV) metallacycle [Th (C H2SiMe2 N SiMe3)(NR2) 2](1; R= SiMe3), with
Ph3P CH2 affords the Th (IV) carbene [Th (CHPPh3)(NR2) 3](2) in good yield. In solution …
Ph3P CH2 affords the Th (IV) carbene [Th (CHPPh3)(NR2) 3](2) in good yield. In solution …
The Th [double bond, length as m-dash] C double bond: an experimental and computational study of thorium poly-carbene complexes
W Ren, X Deng, G Zi, DC Fang - Dalton Transactions, 2011 - pubs.rsc.org
The first thorium poly-carbene complexes [(Ph2PS) 2C] 2Th (DME)(2) and [{[(Ph2PS) 2C]
3Th} Li2 (DME)] n (3) have been prepared and structurally characterized. DFT calculations …
3Th} Li2 (DME)] n (3) have been prepared and structurally characterized. DFT calculations …
[图书][B] Computational spectroscopy: methods, experiments and applications
J Grunenberg - 2011 - books.google.com
Unique in its comprehensive coverage of not only theoretical methods but also applications
in computational spectroscopy, this ready reference and handbook compiles the …
in computational spectroscopy, this ready reference and handbook compiles the …
[HTML][HTML] Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
EP Wildman, G Balázs, AJ Wooles, M Scheer… - Nature …, 2017 - nature.com
Despite a major expansion of uranium–ligand multiple bond chemistry in recent years,
analogous complexes involving other actinides (An) remain scarce. For thorium, under …
analogous complexes involving other actinides (An) remain scarce. For thorium, under …
Formation of unprecedented actinide carbon triple bonds in uranium methylidyne molecules
Chemistry of the actinide elements represents a challenging yet vital scientific frontier.
Development of actinide chemistry requires fundamental understanding of the relative roles …
Development of actinide chemistry requires fundamental understanding of the relative roles …